{"id":"W2314897389","doi":"10.1021/om2005832","title":"Metal-Free Transfer Hydrogenation Catalysis by B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub>","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":116,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Catalysis; Racemization; Transfer hydrogenation; Amine gas treating; Lewis acids and bases; Metal; Hydrogen; Medicinal chemistry; Organic chemistry; Combinatorial chemistry; Ruthenium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","insufficient_payload"],"category_scores_codex":[0.0005867172,0.001685061,0.001621479,0.0004045985,0.0005554355,0.0002780088,0.002167916,0.001484832,0.001888789],"category_scores_gemma":[0.000417457,0.001840019,0.00108955,0.001859526,0.0005629347,0.0009412557,0.000547141,0.001356488,0.001655882],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006621626,"about_ca_system_score_gemma":0.0004139325,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004320201,"about_ca_topic_score_gemma":0.0002048729,"domain_scores_codex":[0.9924158,0.0001290188,0.001795195,0.002239359,0.001595531,0.0018251],"domain_scores_gemma":[0.9946514,0.0001901989,0.0005091296,0.003103738,0.0004296919,0.001115876],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009176244,0.001133263,0.0006401524,0.0004535497,0.001100513,0.00008246263,0.0009141805,0.000004041148,0.9830119,0.0001318127,0.002409765,0.01002658],"study_design_scores_gemma":[0.002343187,0.00007905509,0.0003798251,0.00006811062,0.001417984,0.0001120545,0.0003015807,0.000070581,0.9898182,0.0003396347,0.003013818,0.002055976],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9906599,0.00140857,0.0004144988,0.0004278498,0.0004072585,0.0004131121,0.0007859709,0.0009016289,0.004581202],"genre_scores_gemma":[0.9938098,0.002010962,0.0001389486,0.0005441604,0.0005924634,0.0001378727,0.001900964,0.0005931716,0.0002716767],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007970608,"threshold_uncertainty_score":0.9998115,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01258323222449346,"score_gpt":0.192150847833663,"score_spread":0.1795676156091695,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}