{"id":"W2314974718","doi":"10.1021/om401118n","title":"Ancillary Metal Centers in Frustrated Lewis Pair Chemistry: Ruthenium Acetylide as a Lewis Base in the Activation of CO<sub>2</sub>, Aldehyde, and Alkyne","year":2013,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Alkyne; Acetylide; Chemistry; Ruthenium; Aldehyde; Frustrated Lewis pair; Lewis acids and bases; Medicinal chemistry; Metal; Photochemistry; Polymer chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001825561,0.0003133543,0.0002574309,0.0001602947,0.0002215663,0.000502472,0.0004745948,0.0003302919,0.001557151],"category_scores_gemma":[0.0001449735,0.0001754444,0.0001403695,0.0001145004,0.0004266796,0.0004395336,0.0004781076,0.0003046987,0.0005222393],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002711789,"about_ca_system_score_gemma":0.0001269771,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003166119,"about_ca_topic_score_gemma":0.000735521,"domain_scores_codex":[0.9998817,0.00002804396,0.000005916093,0.00001948352,0.0000274242,0.00003738277],"domain_scores_gemma":[0.9999349,0.00001172257,0.00001470009,0.00001536269,0.000006860208,0.00001644326],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003501527,0.00005319691,0.0002910135,0.0001631548,0.00002430697,0.0004527045,0.0001182305,0.00214212,0.9821714,0.007762359,0.0003345422,0.006136709],"study_design_scores_gemma":[0.0001126412,0.0005904654,0.0005435614,0.000007901043,0.00002140153,0.0004247077,0.00004578706,0.00711578,0.9845739,0.001316817,0.005221813,0.00002522838],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9864931,0.0005169395,0.005809082,0.000072588,0.00002909689,0.00003276659,0.00004948878,0.0001832681,0.00681376],"genre_scores_gemma":[0.996822,0.0001603696,0.001877046,0.00001416755,0.000004960797,0.00001160715,0.00002261849,0.00001279483,0.0010745],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001557151,"threshold_uncertainty_score":0.005209148,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01010966054492082,"score_gpt":0.211293751753017,"score_spread":0.2011840912080962,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}