{"id":"W2314975875","doi":"10.1021/bm200101b","title":"Polyvinylamine-<i>graft</i>-TEMPO Adsorbs onto, Oxidizes, and Covalently Bonds to Wet Cellulose","year":2011,"lang":"en","type":"article","venue":"Biomacromolecules","topic":"Advanced Cellulose Research Studies","field":"Materials Science","cited_by":30,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Covalent bond; Oxidizing agent; Cellulose; Chemistry; Polymer chemistry; Methylglyoxal; Fiber; Cellulose fiber; Oxidized cellulose; Chemical modification; Aldehyde; Organic chemistry; Chemical engineering; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004167684,0.000396165,0.0004191934,0.0002025746,0.0002462323,0.0001022144,0.0005093776,0.0001072047,0.0004257067],"category_scores_gemma":[0.0001991001,0.000345285,0.00007755484,0.0003550406,0.0004393615,0.0002282825,0.0007004311,0.0001136804,0.0005881172],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008159208,"about_ca_system_score_gemma":0.00006865717,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005145706,"about_ca_topic_score_gemma":0.0001682098,"domain_scores_codex":[0.9971619,0.0001455786,0.0004119147,0.0008165144,0.0005450805,0.0009190284],"domain_scores_gemma":[0.99861,0.00009669366,0.0001190579,0.0005763944,0.0001225518,0.0004752773],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001215259,0.0001376966,0.000415712,0.00007044812,0.00002697433,0.0002042354,0.0008066177,3.07073e-7,0.9933727,0.001693219,0.002200264,0.0009502347],"study_design_scores_gemma":[0.0005243474,0.0004382536,0.003060897,0.00005827151,0.00002455242,0.00004786274,0.0001972304,0.00000973668,0.9826162,0.0007595493,0.01180086,0.0004621763],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9878191,0.003624994,0.001763146,0.0002709594,0.0002255998,0.0005227035,0.000130414,0.0002372646,0.005405795],"genre_scores_gemma":[0.9797893,0.0002579762,0.0175657,0.0002078396,0.00009484883,0.00009813753,0.00001289743,0.00005791532,0.001915352],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01580256,"threshold_uncertainty_score":0.9998999,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03019985251936262,"score_gpt":0.2676681741749796,"score_spread":0.237468321655617,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}