{"id":"W2315208353","doi":"10.1021/ol201508e","title":"The Diastereoselective Alkylation of Arenesulfenate Anions Using Homochiral Electrophiles","year":2011,"lang":"en","type":"article","venue":"Organic Letters","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"Connaught Fund","keywords":"Electrophile; Chemistry; Stereoselectivity; Alkylation; Counterion; Lone pair; Substitution reaction; Medicinal chemistry; Stereochemistry; Organic chemistry; Ion; Catalysis; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003152175,0.0005771151,0.0002331547,0.0001864779,0.0001646357,0.0002130951,0.0002407135,0.0002719443,0.001100514],"category_scores_gemma":[0.0001845168,0.0001749801,0.0002262455,0.0001173391,0.0002265402,0.0002832278,0.0002654385,0.0004004816,0.0003934968],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001401149,"about_ca_system_score_gemma":0.0002670743,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000301133,"about_ca_topic_score_gemma":0.0006859125,"domain_scores_codex":[0.9998884,0.00001976154,0.00001235771,0.00001734886,0.00002261579,0.00003940409],"domain_scores_gemma":[0.9999015,0.00001412409,0.00003072219,0.00001199202,0.00002026384,0.00002131619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001069285,0.00001814607,0.0001706107,0.00009064888,0.000008907492,0.0001835235,0.00006944202,0.0001622452,0.9952151,0.0008102827,0.00009122994,0.003073022],"study_design_scores_gemma":[0.00001870699,0.0002245006,0.0002668069,0.000003528063,0.000008970653,0.0001687828,0.00001645135,0.0001366941,0.9968383,0.0000502316,0.002261162,0.00000586742],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9870689,0.001307804,0.006416043,0.0001386941,0.0000767467,0.00006529827,0.0002286026,0.00008406146,0.004613829],"genre_scores_gemma":[0.9888266,0.002007073,0.005310348,0.00006287636,0.00002678547,0.00004673469,0.0002477791,0.00002078742,0.00345093],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001100514,"threshold_uncertainty_score":0.0036816,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02412634606370927,"score_gpt":0.2222383365866591,"score_spread":0.1981119905229498,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}