{"id":"W2315285999","doi":"10.1021/jp2071343","title":"Kinetics of Polymerization of a Liquid with Nanosize Structural Heterogeneities","year":2011,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Polymerization; Kinetics; Glass transition; Enthalpy; Silsesquioxane; Diffusion; Polymer chemistry; Materials science; Chemical engineering; Chemistry; Polymer; Thermodynamics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006040963,0.00009636274,0.0002389349,0.000007313621,0.00001782009,0.000004117701,0.0002946432,0.00003236522,0.0001474778],"category_scores_gemma":[0.00002696122,0.00005511936,0.00007382235,0.00006873022,0.0002924066,0.00006633469,0.00003486142,0.000084092,5.346408e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000008984649,"about_ca_system_score_gemma":0.00002989345,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007813986,"about_ca_topic_score_gemma":1.619349e-7,"domain_scores_codex":[0.9992808,0.00002131868,0.0002858166,0.00005716723,0.0002506125,0.0001043363],"domain_scores_gemma":[0.999072,0.00004808735,0.000497574,0.0001781308,0.0001584553,0.00004571012],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005069878,0.00006817876,0.00007183666,0.00008948441,0.00002072432,0.000001603655,0.001271009,0.00003561253,0.9978985,0.000009613632,0.000005193332,0.00002128538],"study_design_scores_gemma":[0.0002483063,0.0003707269,0.0002116621,0.00005722106,0.00006691497,0.00006726824,0.000360601,0.000009138537,0.9984617,0.00008267016,0.000001536417,0.00006226597],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9993101,0.00008073647,0.0000337551,0.00001703145,0.00001846451,0.00002054999,0.00000938505,0.000003803056,0.0005061689],"genre_scores_gemma":[0.9997034,0.000004232891,0.0001169035,0.000008045106,0.000131493,3.911244e-7,7.869743e-7,0.00000799915,0.00002672845],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009104076,"threshold_uncertainty_score":0.2247702,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0134471242586133,"score_gpt":0.2178805964317537,"score_spread":0.2044334721731404,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}