{"id":"W2315287291","doi":"10.1021/cg200861e","title":"Interfacial Free Energy: An Entropy Portent to Energy Changes","year":2011,"lang":"en","type":"article","venue":"Crystal Growth & Design","topic":"nanoparticles nucleation surface interactions","field":"Earth and Planetary Sciences","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Western Canada Research Grid; University of Calgary","keywords":"Thermodynamics; Nucleation; Surface energy; Chemical physics; Entropy (arrow of time); Thermodynamic free energy; Chemistry; Molecular dynamics; Materials science; Physics; Computational chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005080468,0.0005357969,0.0005309866,0.001497306,0.0004491949,0.001194874,0.0006862296,0.000597094,0.002250896],"category_scores_gemma":[0.002570873,0.0003675082,0.0004330777,0.0008675473,0.001513858,0.001848367,0.0009943158,0.001045109,0.0002797668],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006324912,"about_ca_system_score_gemma":0.0003558753,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009539693,"about_ca_topic_score_gemma":0.0006579025,"domain_scores_codex":[0.9996676,0.00003965586,0.00001637297,0.00007553848,0.0001587571,0.00004216577],"domain_scores_gemma":[0.9993615,0.0003192992,0.0000885831,0.0001189169,0.0000793284,0.00003239455],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"theoretical_or_conceptual","study_design_scores_codex":[0.0003533109,0.000169458,0.01654136,0.0004420844,0.0002110124,0.0005168926,0.0007372523,0.3956421,0.249914,0.2671672,0.001457284,0.06684803],"study_design_scores_gemma":[0.00002236991,0.0001104872,0.01508333,0.00005720698,0.00004099166,0.0003204019,0.0001479965,0.7959024,0.06349353,0.1185325,0.006168977,0.0001198508],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.534903,0.004474206,0.4273646,0.001373997,0.0003578469,0.0001086428,0.0008765344,0.0007510374,0.0297902],"genre_scores_gemma":[0.9852329,0.0006378238,0.01112344,0.00007894898,0.00005076527,0.00005118285,0.0001607628,0.0001625693,0.002501636],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002250896,"threshold_uncertainty_score":0.007530034,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05089133978259008,"score_gpt":0.216775374286004,"score_spread":0.1658840345034139,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}