{"id":"W2315368067","doi":"10.1021/ol200302h","title":"Stereoselective Synthesis of Both Stereoisomers of β-Fluorostyrene Derivatives from a Common Intermediate","year":2011,"lang":"en","type":"article","venue":"Organic Letters","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Stereoselectivity; Chemistry; Stereospecificity; Halogenation; Trimethylsilyl; Silylation; Stereochemistry; Aryl; Fluoride; Cis–trans isomerism; Medicinal chemistry; Organic chemistry; Catalysis; Alkyl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002372406,0.0002827806,0.0005509138,0.00009649642,0.00005212429,0.00000455744,0.0005667557,0.0002295481,0.005587037],"category_scores_gemma":[0.000190862,0.0002843423,0.0001231405,0.0002730959,0.0005426696,0.0001193636,0.0002039044,0.0005103777,0.00004528453],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001116638,"about_ca_system_score_gemma":0.00007333301,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002257512,"about_ca_topic_score_gemma":0.00003134627,"domain_scores_codex":[0.9982455,0.0002886639,0.0005931609,0.0003498564,0.0001700087,0.0003527976],"domain_scores_gemma":[0.9981346,0.0008236862,0.0004585295,0.0003890271,0.00006113714,0.0001329897],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000346459,0.0002829476,0.08081528,0.00007657622,0.0005870418,0.00001958919,0.004850465,6.265788e-7,0.9083441,0.0000191598,0.001010162,0.003647585],"study_design_scores_gemma":[0.0008694585,0.00008676447,0.04114386,0.0000534654,0.0002318417,0.00000685106,0.0004288908,0.00001616335,0.9566543,0.00009824725,0.0001720536,0.0002381754],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976183,0.0001427385,0.0001035908,0.0003214382,0.000461619,0.0001892495,0.0001658527,0.00005952537,0.0009377175],"genre_scores_gemma":[0.9982412,0.00006520811,0.0005055863,0.0009560356,0.0001088183,0.00001786455,0.00001395525,0.00005505816,0.00003625282],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04831012,"threshold_uncertainty_score":0.9999609,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05924095605080761,"score_gpt":0.3320617857157086,"score_spread":0.272820829664901,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}