{"id":"W2315430544","doi":"10.1021/jf502751n","title":"Thermally Induced Oxidative Decarboxylation of Copper Complexes of Amino Acids and Formation of Strecker Aldehyde","year":2014,"lang":"en","type":"article","venue":"Journal of Agricultural and Food Chemistry","topic":"Advanced Glycation End Products research","field":"Biochemistry, Genetics and Molecular Biology","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Strecker amino acid synthesis; Decarboxylation; Aldehyde; Oxidative decarboxylation; Maillard reaction; Alanine; Amino acid; Oxidative deamination; Organic chemistry; Glycine; Schiff base; Acetaldehyde; Oxidative phosphorylation; Copper; Polymer chemistry; Biochemistry; Ethanol","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001121865,0.00007310668,0.0001582348,0.00001511851,0.00001828022,0.000004173344,0.00006997783,0.00007011774,0.000003570331],"category_scores_gemma":[0.00009065905,0.00004647543,0.0000376454,0.00005342688,0.00006993504,0.00002495065,0.00003859661,0.00007171628,3.347218e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000005134175,"about_ca_system_score_gemma":0.0000162058,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001259406,"about_ca_topic_score_gemma":9.697413e-7,"domain_scores_codex":[0.9993971,0.00002571861,0.0002998424,0.00007471508,0.0001373435,0.00006526941],"domain_scores_gemma":[0.9989906,0.00001812886,0.0004413321,0.00006665994,0.0004430399,0.00004023063],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005782221,0.00002793647,0.0007924848,0.0001246158,0.00004207981,2.768133e-8,0.0001374311,0.00003491507,0.9971008,0.00001649718,0.00003032811,0.001635004],"study_design_scores_gemma":[0.0004105202,0.0004164795,0.05209471,0.00004076291,0.00001604926,0.00002853673,0.0003835994,0.000007712663,0.9464165,0.00005414266,0.00007858288,0.00005241235],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9990466,0.0003755735,0.0001457711,0.00008517438,0.00001043858,0.00004412794,0.00001149919,7.497715e-7,0.0002800987],"genre_scores_gemma":[0.9991282,0.0001766249,0.0005549727,0.000004864939,0.00006907707,6.553771e-7,0.00002925102,0.000002783408,0.00003359779],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05130222,"threshold_uncertainty_score":0.1895213,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01465334385347975,"score_gpt":0.253593102704755,"score_spread":0.2389397588512752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}