{"id":"W2315430544","doi":"10.1021/jf502751n","title":"Thermally Induced Oxidative Decarboxylation of Copper Complexes of Amino Acids and Formation of Strecker Aldehyde","year":2014,"lang":"en","type":"article","venue":"Journal of Agricultural and Food Chemistry","topic":"Advanced Glycation End Products research","field":"Biochemistry, Genetics and Molecular Biology","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Strecker amino acid synthesis; Decarboxylation; Aldehyde; Oxidative decarboxylation; Maillard reaction; Alanine; Amino acid; Oxidative deamination; Organic chemistry; Glycine; Schiff base; Acetaldehyde; Oxidative phosphorylation; Copper; Polymer chemistry; Biochemistry; Ethanol","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001901532,0.0004466529,0.0001784068,0.0002541722,0.0001750854,0.0001729059,0.0001788719,0.0002723677,0.0009941411],"category_scores_gemma":[0.0002874838,0.0001627875,0.0002151934,0.0001527941,0.0001938583,0.0002195117,0.0001916753,0.0003245039,0.0001873012],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002214115,"about_ca_system_score_gemma":0.0001642732,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003980863,"about_ca_topic_score_gemma":0.0007535147,"domain_scores_codex":[0.9998423,0.00003420294,0.000007746266,0.0000322471,0.00003291072,0.00005058827],"domain_scores_gemma":[0.999836,0.00002009348,0.00006172917,0.00001894996,0.00003566422,0.00002759628],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001154781,0.00001058231,0.0001379152,0.00004322133,0.000008229159,0.00007819471,0.00003119172,0.00007577092,0.9984895,0.0001592275,0.00003046208,0.0008202011],"study_design_scores_gemma":[0.00000320404,0.00007497129,0.0004826238,0.000001496896,0.000003031679,0.00004940799,0.000006159737,0.0001993222,0.9988908,0.00002290568,0.0002637684,0.000002311852],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935643,0.0008576808,0.003703782,0.0000384081,0.00002464282,0.00002957688,0.00006267765,0.00005792833,0.001661022],"genre_scores_gemma":[0.996268,0.0002030305,0.002019598,0.00002138718,0.000005320428,0.00001114433,0.00007554828,0.000009391073,0.001386613],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009941411,"threshold_uncertainty_score":0.00332576,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01465334385347975,"score_gpt":0.253593102704755,"score_spread":0.2389397588512752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}