{"id":"W2315542309","doi":"10.1021/om100552h","title":"Synthesis and Reactivity of [(PhB(CH<sub>2</sub>PPh<sub>2</sub>)<sub>3</sub>-κ<sup>3</sup><i>P</i>)Ru(NCMe)<sub>3</sub>]PF<sub>6</sub> and Its Potential as a Transfer Hydrogenation Catalyst","year":2010,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University; Lakehead University","funders":"","keywords":"Chemistry; Phosphine; Steric effects; Reactivity (psychology); Ruthenium; Ligand (biochemistry); Acetonitrile; Medicinal chemistry; Catalysis; Stereochemistry; Organic chemistry; Receptor","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001202133,0.0002180819,0.0002659,0.0001594608,0.0001667854,0.0002981164,0.0002990327,0.0004247178,0.001229076],"category_scores_gemma":[0.0003678077,0.0001817266,0.0001162836,0.0002194529,0.0001667041,0.0003627529,0.0001261852,0.0003083116,0.000342708],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003575975,"about_ca_system_score_gemma":0.0001889215,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009593049,"about_ca_topic_score_gemma":0.001170338,"domain_scores_codex":[0.999904,0.00001191932,0.000006723579,0.00002563067,0.00003360549,0.00001808423],"domain_scores_gemma":[0.9999092,0.00001657594,0.00002670698,0.00001597907,0.00001502109,0.00001650586],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001923465,0.00003895377,0.0001759025,0.0001212173,0.00001030478,0.00007378796,0.0000563729,0.0006972156,0.9909807,0.0003583927,0.0001284767,0.007166374],"study_design_scores_gemma":[0.00001238053,0.0001415214,0.0006669376,0.00000380703,0.000007327593,0.0001605031,0.000006536624,0.0005304051,0.9967149,0.00003425126,0.001714107,0.000007335187],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905296,0.001804196,0.004591515,0.00008371089,0.00001476241,0.00004737145,0.0003977291,0.0001192862,0.002411751],"genre_scores_gemma":[0.992672,0.0006512277,0.003985629,0.00002005287,0.000004480878,0.00001732834,0.0004164555,0.0000403642,0.002192479],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001229076,"threshold_uncertainty_score":0.004111648,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006698896298583181,"score_gpt":0.1991443731075588,"score_spread":0.1924454768089756,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}