{"id":"W2315646504","doi":"10.1021/ma202785x","title":"Generic, Metal-Free Cross-Linking and Modification of Silicone Elastomers Using Click Ligation","year":2012,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Sensor and Energy Harvesting Materials","field":"Engineering","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Elastomer; Silicone; Azide; Materials science; Surface modification; Polydimethylsiloxane; Click chemistry; Polymer chemistry; Wetting; Alkyne; Polymer science; Chemical engineering; Composite material; Chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005063014,0.0009353511,0.0002609777,0.00032725,0.0002180563,0.0002450132,0.0004590873,0.0005726903,0.001937666],"category_scores_gemma":[0.0004750951,0.000303337,0.0005122743,0.0003317707,0.0003662053,0.0004966822,0.0005646613,0.000667159,0.001023063],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002184944,"about_ca_system_score_gemma":0.0002202014,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001443231,"about_ca_topic_score_gemma":0.0003100549,"domain_scores_codex":[0.9996321,0.00005197608,0.00003873837,0.00009406538,0.0001031426,0.00007987901],"domain_scores_gemma":[0.9997885,0.00004974803,0.00006839526,0.00004203755,0.00001831996,0.00003303127],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003782833,0.00001869446,0.00005425757,0.00008111284,0.000007001716,0.0001072876,0.00002608106,0.0001252729,0.9964253,0.000398802,0.000108783,0.002609551],"study_design_scores_gemma":[0.000004412274,0.00006230965,0.0001979613,0.000002938435,0.000003804205,0.0001415594,0.000003721806,0.0002285605,0.997578,0.0000394226,0.001732164,0.000005161359],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8037536,0.004211473,0.1800351,0.000382638,0.0002058849,0.0004657017,0.0009734924,0.00187269,0.008099379],"genre_scores_gemma":[0.9313284,0.003222795,0.05599092,0.0002479954,0.00005412728,0.0003590929,0.001204661,0.000184201,0.007407741],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001937666,"threshold_uncertainty_score":0.006482124,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03079623096664245,"score_gpt":0.2697890876578729,"score_spread":0.2389928566912304,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}