{"id":"W2315736249","doi":"10.1021/je500358r","title":"Evaluation of the Vaporization Enthalpies and Liquid Vapor Pressures of (<i>R</i>)-Deprenyl, (<i>S</i>)-Benzphetamine, Alverine, and a Series of Aliphatic Tertiary Amines by Correlation Gas Chromatography at <i>T</i>/K = 298.15","year":2014,"lang":"en","type":"article","venue":"Journal of Chemical & Engineering Data","topic":"Chemical Thermodynamics and Molecular Structure","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Mallinckrodt Pharmaceuticals","keywords":"Chemistry; Enthalpy; Vaporization; Enthalpy of vaporization; Triethylamine; Sublimation (psychology); Standard enthalpy of formation; Diethylamine; Vapor pressure; Analytical Chemistry (journal); Physical chemistry; Chromatography; Organic chemistry; Thermodynamics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003244787,0.0001729187,0.0003580564,0.00004756308,0.00001648477,0.00001110776,0.0003282769,0.0001216902,0.00001679663],"category_scores_gemma":[0.0005067475,0.0001336345,0.00008231176,0.0001169351,0.0001287557,0.0001860862,0.0002771234,0.0001389945,1.683876e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001848926,"about_ca_system_score_gemma":0.00002045103,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007576181,"about_ca_topic_score_gemma":7.721347e-7,"domain_scores_codex":[0.9985138,0.00002724791,0.0005997813,0.0001747243,0.0005725812,0.0001118951],"domain_scores_gemma":[0.9984954,0.0001144369,0.0006454518,0.0004289181,0.0002523956,0.00006338189],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006899284,0.00003781546,0.001070506,0.0004973528,0.0001618398,2.805281e-7,0.00006673606,0.0007575928,0.9964538,0.00002859739,0.00009045771,0.0007660491],"study_design_scores_gemma":[0.0007316282,0.00003866029,0.0005973678,0.0003216531,0.000495027,0.00006499614,0.000008709856,0.03737844,0.9597412,0.0001441975,0.0003585409,0.0001195366],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9949212,0.00340603,0.001270787,0.00004073153,0.00007020613,0.00007626974,0.0001730265,0.000007434298,0.00003433309],"genre_scores_gemma":[0.998899,0.0002576602,0.0005903782,0.000005880034,0.00005589116,0.000002120436,0.0001639978,0.00002120667,0.000003900213],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03671253,"threshold_uncertainty_score":0.5449457,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005893687180698096,"score_gpt":0.2034600770979321,"score_spread":0.197566389917234,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}