{"id":"W2315918402","doi":"10.1021/acs.organomet.6b00158","title":"Metal-Free Phosphine Oxide Reductions Catalyzed by B(C<sub>6</sub>F<sub>5</sub>)<sub>3</sub> and Electrophilic Fluorophosphonium Cations","year":2016,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":80,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Einstein Stiftung Berlin; Deutsche Forschungsgemeinschaft; Deutscher Akademischer Austauschdienst","keywords":"Chemistry; Electrophile; Hydrosilylation; Phosphine; Phosphine oxide; Catalysis; Oxide; Metal; Medicinal chemistry; Reducing agent; Group (periodic table); Reduction (mathematics); Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0004007789,0.001535126,0.001421939,0.000309229,0.0009011349,0.0003143531,0.001532724,0.00105911,0.0007073573],"category_scores_gemma":[0.0009274129,0.001449134,0.0005722249,0.001716547,0.0009642669,0.0008379269,0.0008115021,0.001145229,0.0007914772],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001063449,"about_ca_system_score_gemma":0.0007041603,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008172074,"about_ca_topic_score_gemma":0.0002946616,"domain_scores_codex":[0.9931016,0.00008809068,0.001573866,0.002263942,0.001082548,0.001889961],"domain_scores_gemma":[0.9939851,0.0003301018,0.0007665579,0.003197898,0.0005025468,0.00121783],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008855706,0.0006941982,0.0004115108,0.0002417806,0.0006178394,0.00003581888,0.0001792484,0.000001875432,0.9838606,0.0002049602,0.007527606,0.00613608],"study_design_scores_gemma":[0.00273036,0.00007118325,0.0009382927,0.0001049006,0.0007604734,0.0002951891,0.0001318015,0.00001115897,0.9872485,0.0005388489,0.005388129,0.001781204],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9880481,0.00443234,0.0001767012,0.003768475,0.0004678704,0.0004870886,0.001194127,0.0008893618,0.0005359265],"genre_scores_gemma":[0.9887381,0.00770768,0.0001986636,0.0002789016,0.0007006403,0.0002196058,0.0009347799,0.0005300242,0.0006916287],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004354876,"threshold_uncertainty_score":0.9999865,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005707802573989551,"score_gpt":0.1927105528818263,"score_spread":0.1870027503078368,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}