{"id":"W2316018297","doi":"10.1021/ic049204x","title":"Uranium (III) Scorpionates:  Synthesis and Structure of [(Tp<sup>Me</sup><sub><sup>2</sup></sub>)<sub>2</sub>U{N(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub>}] and [(Tp<sup>Me</sup><sub><sup>2</sup></sub>)<sub>2</sub>U{N(SiMe<sub>3</sub>)<sub>2</sub>}]","year":2004,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Steric effects; Ligand (biochemistry); Crystallography; Bond length; Pentagonal bipyramidal molecular geometry; Actinide; Tetrahydrofuran; X-ray crystallography; Crystal structure; Molecular geometry; Monomer; Amide; Molecule; Stereochemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000064995,0.0003193859,0.0001784184,0.0001215923,0.0001479043,0.0002554615,0.0004363735,0.0002957089,0.001680553],"category_scores_gemma":[0.0001484637,0.0001256026,0.00009363074,0.0002219797,0.0001553576,0.0001595968,0.0002004268,0.0002067045,0.000548011],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000306918,"about_ca_system_score_gemma":0.0002748296,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001993702,"about_ca_topic_score_gemma":0.00216365,"domain_scores_codex":[0.9999417,0.000007389955,0.000004623987,0.00001413851,0.00001830623,0.00001374566],"domain_scores_gemma":[0.9999635,0.000002075074,0.000008801611,0.00000502623,0.000007178132,0.00001345343],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002733356,0.00003385591,0.0002539131,0.0002464343,0.00002064087,0.0002167805,0.0001254959,0.001175911,0.9835591,0.001103928,0.0003627987,0.01262787],"study_design_scores_gemma":[0.00003016912,0.0003372277,0.001266049,0.0000124877,0.00001649073,0.0002864491,0.00004216277,0.001019028,0.9846107,0.0001193016,0.01224728,0.00001259484],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9787339,0.002953073,0.006051758,0.0001302722,0.00004552628,0.0001062068,0.0004267519,0.0002343607,0.01131811],"genre_scores_gemma":[0.9817447,0.001737849,0.005225739,0.00006343904,0.00001561601,0.00004363383,0.000649404,0.00004386381,0.01047574],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001993702,"threshold_uncertainty_score":0.005622029,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007025362018547685,"score_gpt":0.2049380163560229,"score_spread":0.1979126543374752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}