{"id":"W2316018297","doi":"10.1021/ic049204x","title":"Uranium (III) Scorpionates:  Synthesis and Structure of [(Tp<sup>Me</sup><sub><sup>2</sup></sub>)<sub>2</sub>U{N(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub>}] and [(Tp<sup>Me</sup><sub><sup>2</sup></sub>)<sub>2</sub>U{N(SiMe<sub>3</sub>)<sub>2</sub>}]","year":2004,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Chemistry; Steric effects; Ligand (biochemistry); Crystallography; Bond length; Pentagonal bipyramidal molecular geometry; Actinide; Tetrahydrofuran; X-ray crystallography; Crystal structure; Molecular geometry; Monomer; Amide; Molecule; Stereochemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.006351584,0.0185557,0.01554512,0.003682211,0.008025837,0.005196151,0.01190307,0.01517334,0.0006656402],"category_scores_gemma":[0.007821848,0.02159082,0.006916795,0.01157512,0.009227643,0.008668727,0.007038124,0.01926461,0.001519696],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.009830873,"about_ca_system_score_gemma":0.009174562,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000279425,"about_ca_topic_score_gemma":0.000453532,"domain_scores_codex":[0.9317294,0.002559356,0.01620619,0.01973781,0.01260209,0.01716516],"domain_scores_gemma":[0.9513657,0.006916104,0.01107014,0.01378312,0.006456543,0.01040839],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.005077627,0.00484898,0.003290026,0.01504752,0.007697072,0.002676223,0.006076961,0.00895498,0.9052265,0.0001353939,0.01107414,0.02989458],"study_design_scores_gemma":[0.02185383,0.001058408,0.0009481006,0.008952849,0.007315286,0.006408971,0.008706325,0.00636868,0.9145635,0.002577187,0.001592215,0.01965463],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.959229,0.01247494,0.0008029512,0.001923641,0.002013541,0.006562184,0.0100585,0.005081175,0.00185409],"genre_scores_gemma":[0.9523154,0.01805446,0.0005748038,0.002409003,0.01064677,0.002304918,0.008196129,0.005377055,0.0001214463],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01963633,"threshold_uncertainty_score":0.9992577,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007025362018547685,"score_gpt":0.2049380163560229,"score_spread":0.1979126543374752,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}