{"id":"W2316082469","doi":"10.1021/ic062223h","title":"Vanadium(V) Tartrato Complexes:  Speciation in the H<sub>3</sub>O<sup>+</sup>(OH<sup>-</sup>)/H<sub>2</sub>VO<sub>4</sub><sup>-</sup>/(2<i>R</i>,3<i>R</i>)-Tartrate System and X-ray Crystal Structures of Na<sub>4</sub>[V<sub>4</sub>O<sub>8</sub>(<i>rac</i>-tart)<sub>2</sub>]·12H<sub>2</sub>O and (NEt<sub>4</sub>)<sub>4</sub>[V<sub>4</sub>O<sub>8</sub>((<i>R</i>,<i>R</i>)-tart)<sub>2</sub>]·6H<sub>2</sub>O (tart = C<sub>4</sub>H<sub>2</sub>O<sub>6</sub><sup>4</sup><sup>-</sup>)","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Vanadium and Halogenation Chemistry","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Vanadium; Vanadate; Stoichiometry; Aqueous solution; Ligand (biochemistry); Crystallography; Electrospray ionization; Inorganic chemistry; Ionic bonding; Ion; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity"],"category_scores_codex":[0.02514155,0.04222942,0.03504407,0.01508126,0.01846369,0.01381259,0.02725786,0.03030955,0.0006160943],"category_scores_gemma":[0.01136372,0.04895593,0.01942889,0.03188427,0.01989408,0.01872723,0.01507702,0.04173643,0.007558378],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.02556827,"about_ca_system_score_gemma":0.01962145,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009839727,"about_ca_topic_score_gemma":0.008456757,"domain_scores_codex":[0.8434821,0.01125839,0.03959064,0.03787578,0.0292414,0.03855171],"domain_scores_gemma":[0.8885142,0.01505859,0.0269403,0.02996062,0.01535827,0.02416804],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.01104312,0.01183666,0.004266118,0.01813465,0.01328092,0.01011596,0.01288642,0.01975257,0.817067,0.000587778,0.04501944,0.03600933],"study_design_scores_gemma":[0.040706,0.003642962,0.003263939,0.0114213,0.01341931,0.01402591,0.01759425,0.01379987,0.8338951,0.002949593,0.00528762,0.03999412],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9040033,0.01628441,0.002185799,0.003296302,0.008066006,0.02398488,0.02705458,0.01241243,0.002712352],"genre_scores_gemma":[0.8840127,0.03315232,0.0008220849,0.00790771,0.02151976,0.008824596,0.03034098,0.01330369,0.0001161762],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04503209,"threshold_uncertainty_score":0.996964,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008973391894388562,"score_gpt":0.2083028461559744,"score_spread":0.1993294542615858,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}