{"id":"W2316128139","doi":"10.1021/ma501017e","title":"Asymmetric Giant “Bolaform-like” Surfactants: Precise Synthesis, Phase Diagram, and Crystallization-Induced Phase Separation","year":2014,"lang":"en","type":"article","venue":"Macromolecules","topic":"Silicone and Siloxane Chemistry","field":"Materials Science","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Division of Materials Research","keywords":"Silsesquioxane; Polystyrene; Phase diagram; Crystallization; Self-assembly; Polymer; Phase (matter); Polymerization; Materials science; Chemistry; Monomer; Chemical engineering; Polymer chemistry; Crystallography; Nanotechnology; Composite material; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004351869,0.0002630868,0.0003177492,0.0001195318,0.0002171393,0.0002730452,0.0002295841,0.0001354529,0.0002604678],"category_scores_gemma":[0.0006335663,0.0002400129,0.00006098422,0.0003276501,0.00008589403,0.0002867624,0.0000747407,0.00009280464,0.00009046392],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0000411802,"about_ca_system_score_gemma":0.00005119958,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004941928,"about_ca_topic_score_gemma":0.00001188436,"domain_scores_codex":[0.9982935,0.0001172246,0.0003892771,0.0005064506,0.0003185402,0.0003750563],"domain_scores_gemma":[0.9988801,0.0002394065,0.0001754717,0.0004032167,0.0001035382,0.0001982827],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006781798,0.0003113058,0.0000630406,0.00005258439,0.00001051212,0.00001536139,0.0001244349,0.000005562777,0.9753383,0.0001106969,0.0003121746,0.02358822],"study_design_scores_gemma":[0.001554988,0.000161447,0.0001329738,0.00003672284,0.00004732596,0.00003322471,0.0000527972,0.001811031,0.9947073,0.0001868971,0.0009614189,0.0003138145],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9909868,0.0002766925,0.006690927,0.00009828728,0.0001703368,0.0002282345,0.00007103026,0.0001347815,0.001342865],"genre_scores_gemma":[0.9987618,0.00007244998,0.000719409,0.0001224578,0.00008659114,0.00004981144,0.00005790309,0.00003122229,0.00009841008],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02327441,"threshold_uncertainty_score":0.9787441,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01499525872760534,"score_gpt":0.2870285877192481,"score_spread":0.2720333289916427,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}