{"id":"W2316144295","doi":"10.1021/acs.organomet.5b00006","title":"Al Atom Activation of C–S Bonds: Characterization of the Aluminathietane Formed in the Reaction of Al Atoms with 1,2-Butylene Sulfide","year":2015,"lang":"en","type":"article","venue":"Organometallics","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"Laurentian University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Electron paramagnetic resonance; Matrix isolation; Paramagnetism; Sulfide; Density functional theory; Atom (system on chip); Physical chemistry; Photochemistry; Crystallography; Infrared spectroscopy; Computational chemistry; Nuclear magnetic resonance; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001677752,0.0002347207,0.0001404871,0.0002231071,0.0001521189,0.00019782,0.0002338246,0.0002439335,0.001302743],"category_scores_gemma":[0.000227912,0.0001232048,0.0001684276,0.0001528893,0.000230676,0.0001753355,0.0001105299,0.0002444987,0.0001988338],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001491146,"about_ca_system_score_gemma":0.000130741,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005193276,"about_ca_topic_score_gemma":0.000663395,"domain_scores_codex":[0.9999059,0.00001904477,0.000003866517,0.00001568403,0.00003016278,0.00002533939],"domain_scores_gemma":[0.9998865,0.0000276155,0.00002885748,0.000009583016,0.00002804212,0.0000194466],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007834073,0.000007561822,0.0002801442,0.00001350986,0.000003102948,0.00005201064,0.00003128086,0.00004687268,0.9991108,0.00004057923,0.000005282402,0.0003304905],"study_design_scores_gemma":[0.000006892364,0.000157747,0.001698783,0.000001251695,0.000003856746,0.0000523768,0.00003107244,0.0004262906,0.9973935,0.00001736804,0.0002091203,0.000001721669],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985396,0.0001100242,0.0007354255,0.00001471099,0.000004037625,0.000008459704,0.00004369549,0.000009010934,0.0005351067],"genre_scores_gemma":[0.9986904,0.00007284505,0.0004971162,0.000005810702,0.00000230597,0.000004343035,0.00008008272,0.000005904031,0.0006411832],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001302743,"threshold_uncertainty_score":0.004358113,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01312684185985728,"score_gpt":0.2349127647686017,"score_spread":0.2217859229087445,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}