{"id":"W2316413781","doi":"10.1021/pr100771g","title":"Comprehensive Plasma Thiol Redox Status Determination for Metabolomics","year":2010,"lang":"en","type":"article","venue":"Journal of Proteome Research","topic":"Metabolomics and Mass Spectrometry Studies","field":"Biochemistry, Genetics and Molecular Biology","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Metabolomics; Thiol; Redox; Chemistry; Human plasma; Biochemistry; Computational biology; Chromatography; Biology; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001611877,0.0001175734,0.0002641103,0.0002803891,0.0001837238,0.00005505802,0.0002881415,0.0001547153,0.00002005346],"category_scores_gemma":[0.001362332,0.00009357948,0.0001586173,0.000178001,0.0001467214,0.00001058394,0.0001453875,0.0005574997,0.00000346755],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002150819,"about_ca_system_score_gemma":0.0002429412,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004916388,"about_ca_topic_score_gemma":0.00001525646,"domain_scores_codex":[0.99848,0.0001223392,0.0003666642,0.0001973314,0.0003973376,0.0004363473],"domain_scores_gemma":[0.9975505,0.0001172037,0.0002322015,0.0002335683,0.001723242,0.0001432448],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003591675,0.00006198992,0.0002613617,0.00003966006,0.00009298509,0.000003648559,0.00004200871,0.000002958421,0.9909158,0.0004982773,0.001491867,0.006230215],"study_design_scores_gemma":[0.00123611,0.001213588,0.002019117,0.000008858426,0.00002103149,0.00006512146,0.0001873292,0.0001557924,0.6694194,0.00156845,0.3239807,0.000124444],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952547,0.0008399846,0.001989581,0.0004640764,0.0004277136,0.0005938654,0.00002804721,0.000002542856,0.0003994869],"genre_scores_gemma":[0.9453019,0.001697537,0.05124184,0.00003256424,0.00103015,0.00006558702,0.0000125985,0.00002806653,0.0005897511],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3224889,"threshold_uncertainty_score":0.381606,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05090593826639545,"score_gpt":0.384934077970138,"score_spread":0.3340281397037426,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}