{"id":"W2316525498","doi":"10.1021/ja8052046","title":"Reversible Intramolecular C−C Bond Formation/Breaking and Color Switching Mediated by a N,C-Chelate in (2-ph-py)BMes<sub>2</sub> and (5-BMes<sub>2</sub>-2-ph-py)BMes<sub>2</sub>","year":2008,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":212,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Pyridine; Isomerization; Intramolecular force; Boron; Molecule; Chelation; Photochemistry; Medicinal chemistry; Stereochemistry; Crystallography; Inorganic chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008760302,0.0003125774,0.0001654824,0.00007147107,0.0001211658,0.0001834162,0.0002876233,0.0002302017,0.001145369],"category_scores_gemma":[0.000111972,0.000148258,0.0001145608,0.0001187236,0.0001892046,0.0002527201,0.0002164082,0.0002965819,0.0002390314],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002542146,"about_ca_system_score_gemma":0.0001295012,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005650303,"about_ca_topic_score_gemma":0.0012412,"domain_scores_codex":[0.9999281,0.00001077079,0.000002740557,0.00002018568,0.0000124642,0.00002572209],"domain_scores_gemma":[0.9999617,0.000005660561,0.00001382044,0.000003918884,0.000005118906,0.000009713441],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002257476,0.00003455975,0.0001233826,0.0001633802,0.00001139629,0.00005810803,0.00004279848,0.0003073158,0.9943215,0.0006217573,0.0002069553,0.003883129],"study_design_scores_gemma":[0.00002053749,0.0002867971,0.0005315142,0.000004852266,0.000007010149,0.00007518186,0.00001927233,0.001254892,0.9955289,0.00004504882,0.002217432,0.000008530908],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9928196,0.001084193,0.002106824,0.00006650007,0.00004223738,0.00002698991,0.0001313149,0.0001074633,0.003614752],"genre_scores_gemma":[0.9960991,0.0004182336,0.001817824,0.00003719609,0.000005573067,0.00002138527,0.00007505637,0.00001650316,0.001509064],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001145369,"threshold_uncertainty_score":0.003831625,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005363368059439158,"score_gpt":0.2022632482283139,"score_spread":0.1968998801688748,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}