{"id":"W2316592971","doi":"10.1021/es500169x","title":"<i>In Vitro</i> Metabolic Formation of Perfluoroalkyl Sulfonamides from Copolymer Surfactants of Pre- and Post-2002 Scotchgard Fabric Protector Products","year":2014,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University; Environment and Climate Change Canada","funders":"Environment Canada","keywords":"Metabolite; Chemistry; Moiety; Microsome; Copolymer; In vitro; Reagent; Biodegradation; Alkylation; Organic chemistry; Chromatography; Biochemistry; Polymer; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002621683,0.0003784371,0.0001493855,0.0001321305,0.0001014209,0.0002410302,0.0001086974,0.0002157916,0.0006674655],"category_scores_gemma":[0.0002266357,0.0001267475,0.0003469333,0.0001473223,0.0001320677,0.0002109508,0.0001077776,0.0002250766,0.0003061961],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003393057,"about_ca_system_score_gemma":0.0002365633,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00157717,"about_ca_topic_score_gemma":0.002030705,"domain_scores_codex":[0.9997948,0.00005631643,0.00001976906,0.00004311026,0.00005362233,0.00003243324],"domain_scores_gemma":[0.9998492,0.00002858966,0.00006095504,0.00001501875,0.00003468629,0.00001160545],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000205471,0.00001341471,0.0007801516,0.00003355384,0.00001021045,0.00003368638,0.00001732265,0.00005844715,0.9979435,0.00004002166,0.00001410092,0.0008501476],"study_design_scores_gemma":[0.000002113632,0.0002240368,0.003167299,0.000001661453,0.000009331269,0.00006709166,0.00001359372,0.0001646536,0.9959623,0.000009196682,0.0003770102,0.00000165898],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9935684,0.001290795,0.003323481,0.00004190016,0.00001539954,0.0000252562,0.0003174937,0.00003636171,0.001380883],"genre_scores_gemma":[0.9920058,0.0009384165,0.003409673,0.00003796207,0.000009650431,0.00003244453,0.001029846,0.00001513991,0.002521022],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00157717,"threshold_uncertainty_score":0.003136039,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005160218652809114,"score_gpt":0.2144075900471776,"score_spread":0.2092473713943685,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}