{"id":"W2316592971","doi":"10.1021/es500169x","title":"<i>In Vitro</i> Metabolic Formation of Perfluoroalkyl Sulfonamides from Copolymer Surfactants of Pre- and Post-2002 Scotchgard Fabric Protector Products","year":2014,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Per- and polyfluoroalkyl substances research","field":"Environmental Science","cited_by":57,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University; Environment and Climate Change Canada","funders":"Environment Canada","keywords":"Metabolite; Chemistry; Moiety; Microsome; Copolymer; In vitro; Reagent; Biodegradation; Alkylation; Organic chemistry; Chromatography; Biochemistry; Polymer; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["sts"],"consensus_categories":[],"category_scores_codex":[0.0005938248,0.0002144422,0.0003637249,0.0003404691,0.0001465985,0.00001687919,0.0007219358,0.0001395397,0.0005535317],"category_scores_gemma":[0.0001232213,0.0001898355,0.00003583393,0.001151035,0.003859879,0.0009039561,0.0005549451,0.0002319488,0.00008233634],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001779457,"about_ca_system_score_gemma":0.00002616978,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009271173,"about_ca_topic_score_gemma":0.00007546866,"domain_scores_codex":[0.997501,0.0000793144,0.0004337993,0.0006257695,0.000784304,0.0005757981],"domain_scores_gemma":[0.999114,0.00004565627,0.0002172925,0.0005063456,0.000008659099,0.000108071],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006636722,0.0001215292,0.03268424,0.000009074896,0.000002871143,9.924918e-7,0.0004180693,0.00003133428,0.8922251,0.00003520965,0.00001015287,0.07439508],"study_design_scores_gemma":[0.0003281267,0.000151734,0.2037149,0.0000117933,0.000006492109,0.000008181619,0.0001781417,0.0006984957,0.7932101,0.000186178,0.001352992,0.0001528801],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943267,0.004010219,0.00007499552,0.0003172541,0.0000624102,0.0005622432,0.00007735256,0.0000267009,0.0005421338],"genre_scores_gemma":[0.9981076,0.0003537395,0.001259563,0.00004515038,0.0000120696,0.00004033093,0.000006730599,0.00001335779,0.0001615265],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1710307,"threshold_uncertainty_score":0.9988511,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005160218652809114,"score_gpt":0.2144075900471776,"score_spread":0.2092473713943685,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}