{"id":"W2316599864","doi":"10.1021/jo3002479","title":"Sterically Congested Adamantylnaphthalene Quinone Methides","year":2012,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Organic Chemistry Cycloaddition Reactions","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Steric effects; Quinone; Chemistry; Business; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006699762,0.0002975231,0.0004069954,0.00002304571,0.000169519,0.00003876539,0.0007575436,0.0002372539,0.04659703],"category_scores_gemma":[0.000585661,0.0002193409,0.0002014089,0.000275628,0.0002023184,0.0002839526,0.000153378,0.0009592842,0.00008601107],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002718837,"about_ca_system_score_gemma":0.0002125483,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003695725,"about_ca_topic_score_gemma":6.551595e-7,"domain_scores_codex":[0.9979407,0.00004068677,0.0008050837,0.0001392747,0.0005937087,0.0004805456],"domain_scores_gemma":[0.9972641,0.0005325481,0.0008978244,0.0006391416,0.0002864641,0.0003798495],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007119041,0.0002417565,0.0006058573,0.0001126903,0.0002190881,0.00001494619,0.0002802691,0.000001322764,0.9945799,0.000002170053,0.003453919,0.0004168898],"study_design_scores_gemma":[0.0007305989,0.00001209315,0.0004464851,0.0000858093,0.0002970986,0.005804349,0.00131487,0.000002709201,0.976721,0.00003773593,0.01430128,0.0002459718],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9780871,0.001511503,0.0001824954,0.001020282,0.0002215101,0.00003344625,0.00003393213,0.00007378725,0.01883594],"genre_scores_gemma":[0.9943101,0.0002839891,0.0003162149,0.0001078461,0.001680694,0.000001972386,0.00001369421,0.00006096247,0.003224484],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04651102,"threshold_uncertainty_score":0.9542745,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01427814859157745,"score_gpt":0.2384045449262982,"score_spread":0.2241263963347207,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}