{"id":"W2316628913","doi":"10.1021/om500406b","title":"Synthesis and Reactivity of Novel Mesityl Boratabenzene Ligands and Their Coordination to Transition Metals","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Reactivity (psychology); Transition metal; Stereochemistry; Hydrolysis; Ring (chemistry); Metal; Characterization (materials science); Coordination complex; Medicinal chemistry; Combinatorial chemistry; Crystallography; Catalysis; Organic chemistry; Nanotechnology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005434756,0.0002763297,0.0006369646,0.0001898242,0.0001165217,0.00006775993,0.0001711548,0.0001245131,0.001105776],"category_scores_gemma":[0.0003911662,0.0002437879,0.0001059596,0.0004473843,0.00009338417,0.0002267613,0.000108201,0.00009753495,0.00000468341],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003221815,"about_ca_system_score_gemma":0.00002037386,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004643976,"about_ca_topic_score_gemma":0.00003139523,"domain_scores_codex":[0.9987142,0.00002767365,0.0003631771,0.0004642022,0.0002072203,0.0002235368],"domain_scores_gemma":[0.9986838,0.0004052949,0.0001766074,0.000454451,0.000105498,0.0001743238],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002134267,0.0002103068,0.0001098066,0.0001402082,0.000154721,2.193906e-7,0.0004185503,0.000005823284,0.9535118,0.0008881024,0.00000627678,0.04453287],"study_design_scores_gemma":[0.0003275495,0.00003955209,0.003484431,0.00004465786,0.0002844566,0.00001145715,0.0003198361,0.001349821,0.9880948,0.0001851881,0.005532458,0.0003257935],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9844214,0.0002072197,0.01217707,0.0007137596,0.00001986544,0.00008576098,0.000135135,0.00005339129,0.002186361],"genre_scores_gemma":[0.9985454,0.00008464412,0.0008901195,0.00005598059,0.00006285329,0.00002018353,0.00003016058,0.00004076732,0.0002699001],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04420707,"threshold_uncertainty_score":0.9998074,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01372927552754455,"score_gpt":0.2124034790633176,"score_spread":0.198674203535773,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}