{"id":"W2316680441","doi":"10.1021/jacs.5b12823","title":"Stable Borocyclic Radicals via Frustrated Lewis Pair Hydrogenations","year":2016,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":75,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Deutsche Forschungsgemeinschaft","keywords":"Chemistry; Radical; Frustrated Lewis pair; Electron paramagnetic resonance; Boron; Cyclic voltammetry; Photochemistry; Lewis acids and bases; Spectroscopy; Organic chemistry; Catalysis; Physical chemistry; Electrochemistry; Nuclear magnetic resonance","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002559291,0.0002325757,0.0002557939,0.0001476632,0.00026824,0.0004674209,0.0003710586,0.0003610247,0.002474955],"category_scores_gemma":[0.0002125314,0.0001334381,0.0001256926,0.0001180693,0.0003310513,0.000599116,0.0007369905,0.0004773483,0.000533858],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002273119,"about_ca_system_score_gemma":0.0001534348,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001080098,"about_ca_topic_score_gemma":0.0003821829,"domain_scores_codex":[0.9998527,0.00002194324,0.000008570639,0.00002548793,0.00003493159,0.00005637923],"domain_scores_gemma":[0.9999148,0.0000148969,0.0000211303,0.00001970863,0.00001192388,0.00001761752],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002459693,0.00007357444,0.0003181656,0.0005177356,0.00004282095,0.0004054525,0.0003553159,0.001026393,0.9529754,0.02443184,0.001506855,0.01810043],"study_design_scores_gemma":[0.0001265053,0.0007077598,0.0003481306,0.00002733439,0.0000199225,0.0003526287,0.0001022406,0.001912268,0.9656731,0.003513539,0.0271763,0.00004037292],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9676819,0.002380045,0.0163579,0.0004121676,0.0001771769,0.00009502564,0.0002300789,0.0003300971,0.01233566],"genre_scores_gemma":[0.9907485,0.0007781042,0.005400802,0.000107412,0.00002565531,0.00004299452,0.0001031131,0.00004157273,0.002751938],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002474955,"threshold_uncertainty_score":0.008279562,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008567858975181718,"score_gpt":0.2344149587726424,"score_spread":0.2258470997974607,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}