{"id":"W2316696741","doi":"10.1021/jz501378d","title":"Donor–Bridge–Acceptor Proton Transfer in Aqueous Solution","year":2014,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry Letters","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Aqueous solution; Proton; Acceptor; Bridge (graph theory); Transfer (computing); Chemistry; Materials science; Physics; Physical chemistry; Computer science; Nuclear physics; Condensed matter physics; Medicine","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003001771,0.0002514193,0.0003790561,0.00001598825,0.0000998689,0.00002338405,0.000506768,0.00007684406,0.0001025993],"category_scores_gemma":[0.00005343267,0.0001806234,0.0002390299,0.0001198647,0.0001796202,0.000115062,0.00002517222,0.0008350438,0.000005395287],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001275351,"about_ca_system_score_gemma":0.00003543031,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001738322,"about_ca_topic_score_gemma":0.000001750195,"domain_scores_codex":[0.9986168,0.00004264426,0.0004127762,0.0001682228,0.0003546492,0.0004049308],"domain_scores_gemma":[0.9993027,0.0001801145,0.0001020624,0.0002596717,0.00005596619,0.00009947295],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003183688,0.0001789547,0.00013236,0.0003012915,0.0000684496,0.00000787819,0.0006256617,0.0001461712,0.9971608,0.000003939105,0.0002666788,0.0007894422],"study_design_scores_gemma":[0.0009763247,0.00003298598,0.0001216091,0.00009750433,0.00007627239,0.0000715551,0.00004930156,0.0003616552,0.9967502,0.0001107317,0.001145732,0.0002061406],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9948222,0.00008484678,0.0007783487,0.002167074,0.0000221999,0.00007770701,0.000004742353,0.00002192049,0.002020955],"genre_scores_gemma":[0.9987093,0.00002846963,0.000008796776,0.0002001957,0.000960168,0.00002096366,0.000003782617,0.00002188119,0.00004648182],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003887055,"threshold_uncertainty_score":0.7365608,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008345222978342993,"score_gpt":0.2224352393753301,"score_spread":0.2140900163969871,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}