{"id":"W2316696741","doi":"10.1021/jz501378d","title":"Donor–Bridge–Acceptor Proton Transfer in Aqueous Solution","year":2014,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry Letters","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Université de Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Aqueous solution; Proton; Acceptor; Bridge (graph theory); Transfer (computing); Chemistry; Materials science; Physics; Physical chemistry; Computer science; Nuclear physics; Condensed matter physics; Medicine","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001990886,0.0002639513,0.0003646903,0.000125584,0.0004007769,0.000396748,0.0004693436,0.0004847477,0.00092432],"category_scores_gemma":[0.0004972649,0.0002125936,0.000151835,0.0001941004,0.0004905195,0.0008692796,0.0003314644,0.0007687004,0.0001112495],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000512624,"about_ca_system_score_gemma":0.0003960863,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002471497,"about_ca_topic_score_gemma":0.001204391,"domain_scores_codex":[0.9999206,0.000009694607,0.000002837849,0.00002143136,0.00002607826,0.00001924147],"domain_scores_gemma":[0.9998939,0.00005726048,0.00001206379,0.000006077721,0.00001495147,0.00001576928],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007166098,0.0005742799,0.003632812,0.0003391605,0.0001320831,0.0008188679,0.000986171,0.1884622,0.7753985,0.0142723,0.0004823504,0.01418479],"study_design_scores_gemma":[0.0003114194,0.0009398223,0.001370595,0.00001583373,0.0000409802,0.00008250249,0.0002017164,0.7493122,0.2430904,0.003582317,0.001012883,0.00003947633],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9962409,0.00008658032,0.002935757,0.00005305005,0.000007490748,0.00001166183,0.00002751054,0.00002278482,0.0006143962],"genre_scores_gemma":[0.99716,0.0001610735,0.002271853,0.00001796162,0.000003715729,0.00001467388,0.00004937174,0.000006357284,0.0003151192],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002471497,"threshold_uncertainty_score":0.004914224,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008345222978342993,"score_gpt":0.2224352393753301,"score_spread":0.2140900163969871,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}