{"id":"W2316749811","doi":"10.1021/jp206899w","title":"Kinetics Studies of the Gas-Phase Reactions of NO<sub>3</sub>Radicals with Series of 1-Alkenes, Dienes, Cycloalkenes, Alkenols, and Alkenals","year":2011,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"University of British Columbia; National Science Foundation","keywords":"Radical; Gas phase; Series (stratigraphy); Kinetics; Chemistry; Phase (matter); Photochemistry; Organic chemistry; Physics; Geology; Paleontology; Classical mechanics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002436546,0.0005443437,0.0002403175,0.0001483219,0.0001689314,0.0002011343,0.0002698278,0.0002725745,0.001028159],"category_scores_gemma":[0.0003610788,0.0001299916,0.0002619659,0.0001089929,0.0001842597,0.0003614805,0.0001531496,0.0003188459,0.0002392284],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003358656,"about_ca_system_score_gemma":0.0001807061,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001086414,"about_ca_topic_score_gemma":0.001262405,"domain_scores_codex":[0.9998678,0.00001437727,0.000005769896,0.00004440983,0.00004294246,0.00002472939],"domain_scores_gemma":[0.9997916,0.00008116751,0.00005487356,0.000009749965,0.00004342993,0.00001930661],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001990655,0.00001986687,0.001329271,0.0001181305,0.00001685322,0.00003370106,0.00003949985,0.0006306853,0.9951983,0.0001456976,0.00004609381,0.002222827],"study_design_scores_gemma":[0.00001119758,0.0002588327,0.004816989,0.000008543961,0.00002142892,0.0000657396,0.00003248194,0.003230162,0.9897545,0.0001047304,0.001686038,0.000009356022],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920731,0.002215306,0.003761642,0.00004473943,0.00002966706,0.0000567616,0.000522704,0.0000490188,0.001247003],"genre_scores_gemma":[0.9935412,0.001620061,0.00247531,0.0000234131,0.000007548344,0.00005087944,0.0004959824,0.00001623716,0.001769265],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001086414,"threshold_uncertainty_score":0.003439486,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02188248691201076,"score_gpt":0.230429711576702,"score_spread":0.2085472246646912,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}