{"id":"W2316792283","doi":"10.1021/ic400478d","title":"Mono- and Dinuclear Cationic Iridium(III) Complexes Bearing a 2,5-Dipyridylpyrazine (2,5-dpp) Ligand","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organic Light-Emitting Diodes Research","field":"Engineering","cited_by":72,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Iridium; Chemistry; Cationic polymerization; Excited state; Ligand (biochemistry); Luminescence; Electrochemistry; Density functional theory; Photochemistry; Photoluminescence; Crystallography; Physical chemistry; Polymer chemistry; Computational chemistry; Electrode; Catalysis; Organic chemistry; Materials science; Atomic physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001302963,0.0002910089,0.0002948928,0.0000485083,0.0001503348,0.0002462404,0.0003777144,0.0001866374,0.001379987],"category_scores_gemma":[0.00009728292,0.0003126927,0.00004938097,0.0002939453,0.0001247795,0.0002538598,0.0002456679,0.0004918966,0.0005130424],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002180135,"about_ca_system_score_gemma":0.00005651517,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001443583,"about_ca_topic_score_gemma":0.000006687982,"domain_scores_codex":[0.9983827,0.00001055335,0.0003628233,0.0003904962,0.0002951418,0.0005582352],"domain_scores_gemma":[0.9989649,0.00009848802,0.00004755591,0.0005291176,0.00009424279,0.0002656602],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000002375653,0.00002191457,0.001326177,0.0002563721,0.00006380832,0.000004919865,0.0003730177,0.0000117344,0.9931351,0.00001104686,0.004454694,0.00033883],"study_design_scores_gemma":[0.000571586,0.00001119943,0.002980241,0.00005646907,0.00001964712,0.00007580602,0.0001711095,0.005390392,0.9884189,0.00006290191,0.00186858,0.000373116],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919835,0.0008034561,0.00004719065,0.0002854132,0.00009314558,0.0002171265,0.000008364843,0.0005712069,0.005990647],"genre_scores_gemma":[0.9978225,0.0001719477,0.0002732569,0.00003617248,0.0003187357,0.00002861909,0.000018796,0.0001127015,0.001217292],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00583903,"threshold_uncertainty_score":0.9999325,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006509512268613076,"score_gpt":0.2004963536443287,"score_spread":0.1939868413757156,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}