{"id":"W2316905582","doi":"10.1007/s00723-016-0774-8","title":"Electron Transfer Pathways in a Tetrathiafulvalene-Aluminum(III) Porphyrin-Free-Base Porphyrin Triad Studied Using Electron Spin Polarization","year":2016,"lang":"en","type":"article","venue":"Applied Magnetic Resonance","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Prince Edward Island; Brock University","funders":"Natural Sciences and Engineering Research Council of Canada; Ryerson University","keywords":"Chemistry; Porphyrin; Tetrathiafulvalene; Electron paramagnetic resonance; Excited state; Crystallography; Electron transfer; Free base; Photochemistry; Molecular physics; Atomic physics; Nuclear magnetic resonance; Physical chemistry; Molecule; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008236848,0.0005862056,0.0006689493,0.0001784145,0.0001690169,0.0000786259,0.000833957,0.0002907874,0.0004890776],"category_scores_gemma":[0.0001029506,0.0004944452,0.0001276951,0.0006857143,0.0002345235,0.0002147382,0.0001383143,0.0003266823,0.0001029669],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000351561,"about_ca_system_score_gemma":0.0003517184,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001821384,"about_ca_topic_score_gemma":0.00008331191,"domain_scores_codex":[0.9958039,0.0001196541,0.0009211582,0.0011879,0.0006794782,0.001287939],"domain_scores_gemma":[0.9983075,0.0001545752,0.000173851,0.001059721,0.00008725814,0.0002170861],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000581068,0.0002365062,0.0008347587,0.00006082333,0.000005126344,0.0000534611,0.0001397274,0.00001072527,0.9913051,0.002526678,0.0002894107,0.003956674],"study_design_scores_gemma":[0.006204075,0.0003250964,0.008012217,0.0001546792,0.00003613336,0.0000437456,0.00003435328,0.00003991942,0.9807316,0.001886363,0.001818848,0.0007129716],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905274,0.003500113,0.0009046768,0.0002006558,0.0001964529,0.0008837705,0.00008773527,0.0001770047,0.003522184],"genre_scores_gemma":[0.9969987,0.0002807536,0.00118674,0.0001713672,0.0002991646,0.0001954298,0.0000192658,0.00008669864,0.0007618692],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01057344,"threshold_uncertainty_score":0.9997507,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01596240230132448,"score_gpt":0.2332084646782032,"score_spread":0.2172460623768788,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}