{"id":"W2316981898","doi":"10.1021/ol400055v","title":"Total Synthesis of Cladoniamide G","year":2013,"lang":"en","type":"article","venue":"Organic Letters","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Total synthesis; Carbamate; Tandem; Combinatorial chemistry; Stereochemistry; Sequence (biology); Oxidative phosphorylation; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006304474,0.00009953071,0.0002229432,0.00005569665,0.00002472908,0.00001021408,0.00007080618,0.0000541982,0.003379633],"category_scores_gemma":[0.0002057023,0.00007025529,0.00007513996,0.0001444143,0.00006516904,0.00006781137,0.00003022725,0.0001038323,0.0004231252],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003564954,"about_ca_system_score_gemma":0.00002254292,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001128551,"about_ca_topic_score_gemma":0.000001322207,"domain_scores_codex":[0.9993297,0.00001833318,0.0001814754,0.0001732558,0.0001241497,0.0001730957],"domain_scores_gemma":[0.9995232,0.00005612354,0.00005941879,0.0002483804,0.00004904052,0.00006384194],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001196462,0.00003270743,0.0004643406,0.0000517119,0.0000428726,0.000005061042,0.00002921924,7.318673e-8,0.9671387,0.000009458699,0.02659057,0.005623335],"study_design_scores_gemma":[0.0001540956,0.00002810483,0.01699292,0.00005390412,0.00006362447,0.00005850496,0.00002296653,0.000004024476,0.9819039,0.000005050754,0.0006267449,0.0000862091],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9579757,0.00005610153,0.00001049578,0.04132249,0.000103865,0.000196811,0.000002732791,0.00003566739,0.0002960869],"genre_scores_gemma":[0.9956731,0.00001312605,0.0007121692,0.003127931,0.0001706328,0.000001062227,0.000001925186,0.00001857878,0.00028147],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03819456,"threshold_uncertainty_score":0.9975314,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005880333038744229,"score_gpt":0.1934210127033088,"score_spread":0.1875406796645646,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}