{"id":"W2316981898","doi":"10.1021/ol400055v","title":"Total Synthesis of Cladoniamide G","year":2013,"lang":"en","type":"article","venue":"Organic Letters","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Total synthesis; Carbamate; Tandem; Combinatorial chemistry; Stereochemistry; Sequence (biology); Oxidative phosphorylation; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001366836,0.000703994,0.0004036939,0.0004143993,0.0002431155,0.0002341477,0.0003045485,0.0002274637,0.002132032],"category_scores_gemma":[0.0001337307,0.0001478294,0.000234764,0.000380689,0.0001691223,0.0001974136,0.0003833133,0.000376993,0.001138918],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004907004,"about_ca_system_score_gemma":0.000735643,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001954214,"about_ca_topic_score_gemma":0.00358713,"domain_scores_codex":[0.999904,0.000009916868,0.000007301147,0.00001765935,0.0000263339,0.0000347752],"domain_scores_gemma":[0.9999343,0.000004911518,0.000006496728,0.000009952822,0.00002112578,0.00002319317],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001558509,0.00004428942,0.000136442,0.0002638097,0.00002248607,0.000254915,0.00005060805,0.001519144,0.9803847,0.000845216,0.0005903173,0.01573215],"study_design_scores_gemma":[0.00008674079,0.0009132627,0.001723346,0.00005329684,0.00005269129,0.0003111045,0.00004395742,0.001791717,0.9577883,0.0003617331,0.03684452,0.00002932782],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8827305,0.00633991,0.0470586,0.0002494177,0.000264328,0.001511303,0.00971447,0.0007934336,0.05133804],"genre_scores_gemma":[0.9634492,0.004617769,0.01796701,0.0001548469,0.00001519031,0.0003386183,0.003021218,0.00006860317,0.0103676],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002132032,"threshold_uncertainty_score":0.007132351,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005880333038744229,"score_gpt":0.1934210127033088,"score_spread":0.1875406796645646,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}