{"id":"W2317029726","doi":"10.1021/ja309153x","title":"Besting Vitamin E: Sidechain Substitution is Key to the Reactivity of Naphthyridinol Antioxidants in Lipid Bilayers","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Molecular Sensors and Ion Detection","field":"Chemistry","cited_by":63,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Brock University; University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Lipophilicity; Liposome; Lipid bilayer; Photochemistry; Stereochemistry; Organic chemistry; Membrane; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005588056,0.000119307,0.0002654129,0.00002076958,0.00006890256,0.00001231692,0.0002947848,0.00006559156,0.00001911349],"category_scores_gemma":[0.0004175712,0.00007172851,0.0003926267,0.0004517214,0.0001697756,0.0000996129,0.00009230656,0.0004802888,0.000001781368],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001990639,"about_ca_system_score_gemma":0.00004029155,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001420133,"about_ca_topic_score_gemma":0.000001584242,"domain_scores_codex":[0.9988182,0.0000578042,0.0003851294,0.0001092149,0.000380684,0.0002490222],"domain_scores_gemma":[0.9987166,0.0001342257,0.000725585,0.0002444519,0.00008549864,0.00009364522],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004732268,0.00009825562,0.01037333,0.00001454782,0.00003531352,5.250318e-7,0.0007217122,0.00005342341,0.9841181,0.00000247979,0.001164369,0.003370639],"study_design_scores_gemma":[0.0002063856,0.00002224306,0.006417458,0.00008152305,0.00002891306,0.00005049234,0.0007181615,0.0002553571,0.990201,0.000009169124,0.001919645,0.0000896802],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977583,0.00005652664,0.0002725981,0.001615091,0.0001151388,0.00004682824,0.000004702136,0.00000620434,0.0001245556],"genre_scores_gemma":[0.9983127,0.00004406155,0.0008494342,0.0004290343,0.0003261489,0.000001732648,2.337194e-7,0.00001193599,0.00002473862],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006082886,"threshold_uncertainty_score":0.2925004,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01352836169605956,"score_gpt":0.2512601388430064,"score_spread":0.2377317771469468,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}