{"id":"W2317338893","doi":"10.1021/acs.jpcc.5b00949","title":"Mechanistic Similarity in Catalytic N<sub>2</sub>Production from NH<sub>3</sub>and NO<sub>2</sub><sup>–</sup>at Pt(100) Thin Films: Toward a Universal Catalytic Pathway for Simple N-Containing Species, and Its Application to<i>in Situ</i>Removal of NH<sub>3</sub>Poisons","year":2015,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":64,"is_retracted":false,"has_abstract":true,"ca_institutions":"Institut National de la Recherche Scientifique","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Electrochemistry; Catalysis; Chemistry; Adsorption; Reaction intermediate; Oxide; Inorganic chemistry; Materials science; Electrode; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001351624,0.0002405059,0.0001574483,0.0001047024,0.0001147049,0.000295515,0.0004165185,0.0006280697,0.001024203],"category_scores_gemma":[0.0002689502,0.0002158848,0.0001810607,0.00006327365,0.0003674146,0.0003745681,0.0001786831,0.0004575773,0.0001635236],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003005782,"about_ca_system_score_gemma":0.0001465375,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004317326,"about_ca_topic_score_gemma":0.000648322,"domain_scores_codex":[0.9998899,0.00001176089,0.000007918424,0.00003286907,0.00003992701,0.00001766703],"domain_scores_gemma":[0.9999319,0.0000214157,0.00001799519,0.00000986995,0.00001173599,0.000007142752],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008752033,0.00001802531,0.0005144019,0.00009738732,0.000007296773,0.000123528,0.00004765855,0.0002459883,0.9968645,0.0005469061,0.00004837238,0.001398482],"study_design_scores_gemma":[0.000005234405,0.0001134292,0.003620173,0.000004407962,0.00001032408,0.0002456418,0.00006495466,0.002957508,0.9914272,0.0004151902,0.001130597,0.000005440066],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9816032,0.0008926775,0.01061286,0.0002304631,0.00006449099,0.00006544313,0.0002534183,0.0001083088,0.006169172],"genre_scores_gemma":[0.9954249,0.0003362875,0.002721916,0.00006101837,0.000004278099,0.00002192948,0.0001014178,0.00001044944,0.001317772],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001024203,"threshold_uncertainty_score":0.003426373,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01682998713214196,"score_gpt":0.2188639658896275,"score_spread":0.2020339787574856,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}