{"id":"W2317369246","doi":"10.1055/s-2009-1216410","title":"Relative and Absolute Structures of Diospongin A, B and C","year":2009,"lang":"en","type":"article","venue":"Planta Medica","topic":"Natural product bioactivities and synthesis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Institute on Drug Abuse; Agricultural Research Service; University of British Columbia; University of Illinois at Urbana-Champaign; Chinese Academy of Sciences; Kurukshetra University; University of Illinois at Chicago; National Oceanic and Atmospheric Administration; U.S. Food and Drug Administration; National Science Foundation of Sri Lanka; University of Colombo; U.S. Department of Agriculture; Western Carolina University; International Science Council; National Center for Complementary and Alternative Medicine; China Academy of Traditional Chinese Medicine; National Institutes of Health; National Center for Research Resources; National Institute of Allergy and Infectious Diseases; Türkiye Bilimsel ve Teknolojik Araştırma Kurumu; Hong Kong Polytechnic University; National Science Foundation; Deutsche Krebshilfe; National Natural Science Foundation of China; Tata Trusts; University Grants Commission; Wake Forest University","keywords":"Chemistry; Absolute configuration; Stereochemistry; Diarylheptanoids; Osteoclast; NMR spectra database; Spectral line; In vitro; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003685696,0.0003525235,0.0002584851,0.0004338122,0.0002260211,0.0004525858,0.000396734,0.0004477147,0.007554935],"category_scores_gemma":[0.0002579029,0.0001382034,0.0002417137,0.0002515096,0.0003367644,0.0002800203,0.0001436626,0.0007900628,0.0006399775],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002798791,"about_ca_system_score_gemma":0.0005067192,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001074057,"about_ca_topic_score_gemma":0.002300532,"domain_scores_codex":[0.9999119,0.00003488858,0.000006468892,0.00001972653,0.00000921736,0.00001791256],"domain_scores_gemma":[0.9998809,0.00002149026,0.00001568402,0.00001082816,0.00001170201,0.00005937932],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.1227909,0.01278161,0.002247545,0.002606298,0.0004919151,0.0005694757,0.0002087197,0.001095288,0.6632962,0.005924912,0.003988101,0.1839991],"study_design_scores_gemma":[0.1040214,0.4761156,0.02723844,0.0003651589,0.001144919,0.001842864,0.0004698469,0.002409234,0.2958034,0.003397009,0.08707899,0.0001131768],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9705865,0.009106214,0.003913528,0.0007734629,0.0002677935,0.001481797,0.002265076,0.0001034432,0.01150228],"genre_scores_gemma":[0.9761522,0.005057437,0.004261098,0.0005074607,0.00006906175,0.0004604084,0.001361644,0.00002009005,0.0121107],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007554935,"threshold_uncertainty_score":0.0252738,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00499200683497432,"score_gpt":0.2167879361012404,"score_spread":0.2117959292662661,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}