{"id":"W2317374997","doi":"10.1021/jp301015b","title":"Bimolecular Rate Constant and Product Branching Ratio Measurements for the Reaction of C<sub>2</sub>H with Ethene and Propene at 79 K","year":2012,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":40,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Photoionization; Chemistry; Propene; Reaction rate constant; Branching (polymer chemistry); Analytical Chemistry (journal); Photodissociation; Mass spectrum; Branching fraction; Acetylene; Photochemistry; Radical; Mass spectrometry; Ion; Ionization; Kinetics; Atomic physics; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004459052,0.0005568331,0.0003502337,0.0005097494,0.0002718178,0.0003018375,0.0007547466,0.0004550896,0.00275178],"category_scores_gemma":[0.0008334701,0.0002414164,0.0002869947,0.0003949933,0.0002337713,0.0005352395,0.0002134921,0.0004629245,0.0005091274],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008959365,"about_ca_system_score_gemma":0.0002454902,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00165199,"about_ca_topic_score_gemma":0.001251246,"domain_scores_codex":[0.9997239,0.00001776635,0.000009857945,0.00008877814,0.0001105896,0.0000490517],"domain_scores_gemma":[0.9995791,0.0001439306,0.0001130574,0.00002765753,0.0001062336,0.00002987031],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002973226,0.00003415431,0.003813728,0.00008124867,0.00002893195,0.00009467568,0.00008173908,0.0009373344,0.9905619,0.0003286827,0.0001013921,0.003638788],"study_design_scores_gemma":[0.000009813988,0.0001203447,0.006800078,0.00000349782,0.00001808432,0.000106085,0.00003688772,0.004128594,0.9879409,0.00006317968,0.000760162,0.0000124149],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9893896,0.000974797,0.006777195,0.00003630341,0.0000151221,0.00005023985,0.0007218794,0.0001815616,0.001853414],"genre_scores_gemma":[0.9948606,0.0006647391,0.002628583,0.00001488136,0.000005342477,0.000038814,0.0005982515,0.00004613155,0.001142714],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00275178,"threshold_uncertainty_score":0.00920558,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01745627700970701,"score_gpt":0.2450073353319989,"score_spread":0.2275510583222919,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}