{"id":"W2317589235","doi":"10.1021/ac200636y","title":"Mass Transport in a Micro Flow-Through Vial of a Junction-at-the-Tip Capillary Electrophoresis-Mass Spectrometry Interface","year":2011,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":68,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Capillary electrophoresis; Analytical Chemistry (journal); Analyte; Mass spectrometry; Capillary action; Volumetric flow rate; Laminar flow; Chromatography; Capillary electrophoresis–mass spectrometry; Electrophoresis; Mechanics; Electrospray ionization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001249903,0.0002744531,0.0003747625,0.00005197184,0.00005641636,0.000007584014,0.0003427207,0.0002159635,0.002043908],"category_scores_gemma":[0.0000160079,0.0002476255,0.0001924499,0.0006417112,0.0001809696,0.00005288209,0.00002382208,0.0004242442,0.00005326613],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000247718,"about_ca_system_score_gemma":0.00005734785,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007619814,"about_ca_topic_score_gemma":0.000009937205,"domain_scores_codex":[0.9983917,0.00001655871,0.0005309426,0.0003493601,0.0002207282,0.0004906374],"domain_scores_gemma":[0.9992453,0.00004576803,0.00005247611,0.0005064011,0.00004776752,0.0001023194],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000829056,0.00006374675,0.0007520877,0.0001084988,0.0001289579,0.00001639699,0.0001567208,0.00004767551,0.9883679,0.00009684482,0.01014971,0.00002852051],"study_design_scores_gemma":[0.0003163058,0.00003317973,0.0005496677,0.00002281316,0.0000962214,0.00002638373,0.00008309988,0.0007776615,0.9916692,0.000724613,0.005436519,0.0002643586],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9423757,0.01604095,0.01467014,0.0000962171,0.00005287244,0.0001836137,0.00002623764,0.0001081909,0.02644606],"genre_scores_gemma":[0.9889556,0.00910062,0.0007016575,0.00003945212,0.00009265559,0.00003743366,0.00004090742,0.00005235278,0.0009793078],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0465799,"threshold_uncertainty_score":0.9999976,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00890795362085908,"score_gpt":0.204597112284809,"score_spread":0.1956891586639499,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}