{"id":"W2317809509","doi":"10.1021/om1011038","title":"Isomeric Dipyrrinato and Dipyrromethanato Boranes","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":24,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Chemistry; Boranes; Hydride; Borane; Borohydride; Isomerization; Adduct; Medicinal chemistry; Boron; Photochemistry; Ligand (biochemistry); Stereochemistry; Hydrogen; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000199596,0.0003015332,0.0002045157,0.0001288043,0.0001279338,0.0002126413,0.000307866,0.0003037746,0.002350905],"category_scores_gemma":[0.0001911036,0.0002457511,0.0001448622,0.0001207746,0.0001648592,0.0002125951,0.0001852757,0.0004244832,0.0005249913],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003171724,"about_ca_system_score_gemma":0.0001287953,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003475359,"about_ca_topic_score_gemma":0.0006458394,"domain_scores_codex":[0.99979,0.00002968768,0.000015282,0.00005522975,0.00004788707,0.00006196675],"domain_scores_gemma":[0.9999131,0.00001312439,0.00002699462,0.000009738938,0.00001348558,0.00002361734],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001611833,0.00001160781,0.00006002376,0.00004492576,0.000005400974,0.00002696534,0.00001461257,0.00006006453,0.9988332,0.0001494102,0.00004529379,0.0005872775],"study_design_scores_gemma":[0.00002037052,0.0002415059,0.0004230943,0.000002005267,0.000007072473,0.0001071211,0.00001434914,0.0003711936,0.9975392,0.00002223105,0.00124749,0.000004519361],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943921,0.0007819085,0.001914792,0.00005989986,0.00003554043,0.00003126046,0.000208311,0.00008499987,0.002491211],"genre_scores_gemma":[0.9918029,0.0005148922,0.002942825,0.00004890638,0.000008265105,0.00003106076,0.000414347,0.00003155676,0.00420532],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002350905,"threshold_uncertainty_score":0.007864535,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02780606601658563,"score_gpt":0.2023764048918766,"score_spread":0.174570338875291,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}