{"id":"W2318013262","doi":"10.1021/ic200090u","title":"N−H Activation in N-Nitropropionamide: Coordination Chemistry of a Primary Nitroamide","year":2011,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Chemical Reactions and Isotopes","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Chemistry; Primary (astronomy); Coordination complex; Medicinal chemistry; Stereochemistry; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001919686,0.0001659471,0.0002342659,0.00003037011,0.00004675853,0.000004673997,0.0002112378,0.0003701227,0.004771319],"category_scores_gemma":[0.0002025437,0.0001751646,0.00006753577,0.0002961507,0.0001390564,0.0001197262,0.00007926445,0.0006206582,0.0000218303],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002591967,"about_ca_system_score_gemma":0.0001315576,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007857935,"about_ca_topic_score_gemma":0.000002043113,"domain_scores_codex":[0.9989395,0.00003211777,0.0004007408,0.0002565581,0.0001316937,0.000239441],"domain_scores_gemma":[0.999279,0.0001233775,0.0001910598,0.000203104,0.0001075603,0.00009584692],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001433489,0.000455094,0.009577016,0.0002103528,0.00003501014,0.000004282449,0.0002359621,0.000002217207,0.9858612,0.00002778436,0.0003927704,0.003054928],"study_design_scores_gemma":[0.0009285116,0.000011401,0.007481254,0.00003401511,0.00002923948,0.00001389241,0.000140311,0.00007804589,0.9873018,0.0005667872,0.003245753,0.0001689455],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9488904,0.00008044903,0.0000443762,0.00009517931,0.00006728662,0.0001231275,0.00001261934,0.00005086027,0.05063564],"genre_scores_gemma":[0.9980935,0.00004253503,0.0001460292,0.0001235724,0.00009582399,0.00003035369,0.00007648854,0.00001953587,0.001372113],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04926353,"threshold_uncertainty_score":0.9961385,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07662499907598305,"score_gpt":0.3424553242173798,"score_spread":0.2658303251413967,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}