{"id":"W2318017210","doi":"10.1021/ja2107965","title":"The Mechanism of Alkene Addition to a Nickel Bis(dithiolene) Complex: The Role of the Reduced Metal Complex","year":2012,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Chemistry; Alkene; Adduct; Nickel; Metal; Decomposition; Ligand (biochemistry); Reaction mechanism; Stereochemistry; Medicinal chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009262229,0.0003724324,0.0003084368,0.0001742611,0.0003633181,0.0004881472,0.0008370393,0.0005825523,0.003101336],"category_scores_gemma":[0.0001970679,0.0002183482,0.0001853508,0.00008461757,0.0004197699,0.0005879651,0.0003447577,0.0005061231,0.0007560127],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006763184,"about_ca_system_score_gemma":0.0002158576,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009929106,"about_ca_topic_score_gemma":0.001308226,"domain_scores_codex":[0.999915,0.000009673164,0.000004253118,0.00002351127,0.00002141099,0.0000261029],"domain_scores_gemma":[0.999953,0.00001181385,0.000009043504,0.000006670883,0.000006426641,0.00001301597],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004867087,0.000149001,0.0009837964,0.0005363699,0.0000621692,0.0008547703,0.0004909134,0.003766519,0.9682576,0.01651109,0.0008079037,0.007093093],"study_design_scores_gemma":[0.0000722961,0.0003353075,0.001194657,0.00001699313,0.00003532191,0.0005754756,0.0001537155,0.01308977,0.9777188,0.001344347,0.005427614,0.00003583052],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9855552,0.0007603384,0.005078724,0.0003726868,0.00006286089,0.00008738922,0.0001481021,0.0001997162,0.007735009],"genre_scores_gemma":[0.995922,0.0003104935,0.000999479,0.0000321258,0.000005768646,0.00002188994,0.00006379457,0.00001270161,0.002631752],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003101336,"threshold_uncertainty_score":0.01037502,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02062808678100234,"score_gpt":0.2666233853314792,"score_spread":0.2459952985504769,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}