{"id":"W2318048695","doi":"10.1021/ol501443m","title":"Efficient Generation and Increased Reactivity in Cationic Gold via Brønsted Acid or Lewis Acid Assisted Activation of an Imidogold Precatalyst","year":2014,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Institute of General Medical Sciences; Alberta Machine Intelligence Institute; National Institutes of Health; National Science Foundation","keywords":"Cationic polymerization; Chemistry; Lewis acids and bases; Brønsted–Lowry acid–base theory; Reactivity (psychology); Catalysis; Phthalimide; Combinatorial chemistry; Reaction conditions; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003003485,0.0004878457,0.0002296455,0.0002330534,0.0001461586,0.0002215551,0.0004339151,0.0004858178,0.001409115],"category_scores_gemma":[0.0003693182,0.0002125563,0.0002760489,0.0001668776,0.0002927434,0.0002671421,0.0004170797,0.0004861511,0.0004929192],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002549894,"about_ca_system_score_gemma":0.0002278392,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000398599,"about_ca_topic_score_gemma":0.000859104,"domain_scores_codex":[0.9997857,0.00002336505,0.00001827934,0.00005623531,0.00006873962,0.00004766147],"domain_scores_gemma":[0.9998773,0.00002581589,0.00002928762,0.00002287939,0.00002514567,0.00001952819],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002389475,0.000003801248,0.00002349553,0.00004842493,0.000002565539,0.00004722915,0.00001834471,0.00005622326,0.9985416,0.0001265889,0.00003358044,0.001074096],"study_design_scores_gemma":[0.000003949778,0.00005079391,0.00009774605,0.000001561184,0.000002644464,0.00005572228,0.000002725436,0.0002069864,0.9991339,0.00001942335,0.0004221538,0.000002517364],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9701744,0.001624852,0.02058153,0.000190782,0.00007937361,0.00008518136,0.0002007311,0.0004711621,0.006592059],"genre_scores_gemma":[0.9876744,0.0005296836,0.008328544,0.00005492068,0.00001304179,0.00002611242,0.0001517693,0.00005435554,0.003167085],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001409115,"threshold_uncertainty_score":0.004713953,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01284122895924016,"score_gpt":0.2220709400927269,"score_spread":0.2092297111334868,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}