{"id":"W2318174119","doi":"10.1021/cs5005823","title":"Metal-Free Photocatalytic Radical Trifluoromethylation Utilizing Methylene Blue and Visible Light Irradiation","year":2014,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":240,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation","keywords":"Trifluoromethylation; Chemistry; Photocatalysis; Photochemistry; Photoredox catalysis; Methylene blue; Catalysis; Photosensitizer; Moiety; Flash photolysis; Trifluoromethyl; Methylene; Transition metal; Combinatorial chemistry; Organic chemistry; Kinetics; Reaction rate constant","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002862478,0.0003216401,0.0001575629,0.0001926545,0.000141334,0.000129684,0.0004173134,0.000461334,0.001036949],"category_scores_gemma":[0.0002014072,0.0001454943,0.0001898428,0.0001337423,0.0002064231,0.0003572072,0.0002979249,0.0003625144,0.0002326174],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003081271,"about_ca_system_score_gemma":0.0002433681,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009032518,"about_ca_topic_score_gemma":0.002021953,"domain_scores_codex":[0.9998586,0.00001766128,0.000007691272,0.00003640528,0.00003878612,0.00004080939],"domain_scores_gemma":[0.9999259,0.00001741436,0.00002653702,0.00001079701,0.00001126731,0.000008049918],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003163023,0.000008466645,0.00004767744,0.00004261833,0.000003903192,0.00003553902,0.00002860004,0.0001057754,0.9969553,0.0002311323,0.00004888284,0.002460463],"study_design_scores_gemma":[0.000004112023,0.00007997006,0.0001727172,0.00000254873,0.000002997955,0.00006791738,0.000005570613,0.0003489098,0.9983447,0.00002561732,0.000940919,0.00000399056],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9612914,0.002315815,0.03091441,0.0001748902,0.0000291348,0.00007187376,0.0001813712,0.000310578,0.00471066],"genre_scores_gemma":[0.9871559,0.0009160061,0.009468514,0.00004599816,0.000006740975,0.00003023949,0.0001393244,0.00002200698,0.002215234],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001036949,"threshold_uncertainty_score":0.003468931,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04548918214949158,"score_gpt":0.3582691500108454,"score_spread":0.3127799678613538,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}