{"id":"W2318333128","doi":"10.1021/jz401310j","title":"Dissociative Adsorption of Nitric Acid at the Surface of Amorphous Solid Water Revealed by X-ray Absorption Spectroscopy","year":2013,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry Letters","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"","keywords":"Nitric acid; Adsorption; Dissociation (chemistry); Chemistry; Amorphous solid; Spectroscopy; Metastability; Ionic bonding; Ionic liquid; Absorption spectroscopy; Inorganic chemistry; Analytical Chemistry (journal); Physical chemistry; Ion; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005084346,0.0001691494,0.0001036658,0.0001671686,0.0001533475,0.0002096749,0.000180729,0.0001643683,0.001207124],"category_scores_gemma":[0.0001039562,0.0001265185,0.00008513434,0.0001001872,0.0002171933,0.000150518,0.0001415738,0.0002232275,0.0001631144],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001048714,"about_ca_system_score_gemma":0.00006602317,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009230294,"about_ca_topic_score_gemma":0.0009139251,"domain_scores_codex":[0.9999462,0.000003949643,0.000001688337,0.0000123303,0.00002050038,0.00001534573],"domain_scores_gemma":[0.9999654,0.00001154252,0.00000714723,0.000003071529,0.000006860188,0.000005837261],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003169452,0.000006159316,0.0007759014,0.00001335543,0.000003803119,0.00004418834,0.00002731431,0.00004852936,0.9983826,0.0000692676,0.00001357129,0.0005836289],"study_design_scores_gemma":[0.000006694989,0.00008842574,0.02022322,0.000003817047,0.000008600398,0.0001328118,0.0001460829,0.002153462,0.9764597,0.0001123523,0.0006598923,0.000004900588],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981274,0.0001863574,0.0006282835,0.00001244554,0.000002696818,0.000004093632,0.00007170144,0.00000907104,0.0009579704],"genre_scores_gemma":[0.9987436,0.0001192218,0.0003425521,0.000009415809,0.00000165032,0.000003992456,0.00007571875,0.000003241485,0.000700613],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001207124,"threshold_uncertainty_score":0.004038215,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004673447655922431,"score_gpt":0.2266014275398633,"score_spread":0.2219279798839409,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}