{"id":"W2318484563","doi":"10.1021/om501023r","title":"The Platinum Center is a Stronger Nucleophile than the Free Nitrogen Donors in a Dimethylplatinum Complex with a Dipyridylpyridazine Ligand","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Oxidative addition; Pyridazine; Medicinal chemistry; Ligand (biochemistry); Platinum; Nucleophile; Bromine; Stereochemistry; Methyl group; Trans effect; Alkyl; Crystallography; Organic chemistry; Crystal structure; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002097657,0.000354984,0.0002565907,0.0001333263,0.0001847025,0.0004785937,0.0007537417,0.0003811607,0.0015105],"category_scores_gemma":[0.0002109911,0.0003505113,0.0001496912,0.0001342398,0.0003114746,0.0003274594,0.0004626106,0.0004892214,0.0003889761],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007911043,"about_ca_system_score_gemma":0.0002573657,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009214723,"about_ca_topic_score_gemma":0.001368809,"domain_scores_codex":[0.9998249,0.00002304222,0.00001696042,0.00004846479,0.00005176457,0.00003494225],"domain_scores_gemma":[0.9999049,0.00001743749,0.00002462399,0.00001493248,0.000008202818,0.00002979792],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001732713,0.00002315224,0.0001199634,0.00009516792,0.00001285971,0.00008640267,0.00004312133,0.000334651,0.9967476,0.0008032194,0.00007869775,0.001481902],"study_design_scores_gemma":[0.00005944871,0.0001906736,0.0003239736,0.000004501592,0.00001609148,0.0001071372,0.000009838572,0.001526706,0.9955294,0.00005109768,0.00217323,0.000007914786],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929986,0.0003454249,0.004264755,0.0001246138,0.0000429132,0.00004083099,0.00006927732,0.0001260746,0.001987431],"genre_scores_gemma":[0.9915336,0.0002194018,0.004619847,0.00003384149,0.00000795952,0.00002817759,0.0001068147,0.00002350911,0.003426826],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0015105,"threshold_uncertainty_score":0.005739868,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01065709986176201,"score_gpt":0.2011918062728128,"score_spread":0.1905347064110508,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}