{"id":"W2318592744","doi":"10.1021/je201354k","title":"Solubility of<scp>l</scp>-Phenylalanine Anhydrous and Monohydrate Forms: Experimental Measurements and Predictions","year":2012,"lang":"en","type":"article","venue":"Journal of Chemical & Engineering Data","topic":"Phase Equilibria and Thermodynamics","field":"Engineering","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"UNIQUAC; Solubility; Anhydrous; Acetone; Chemistry; Solvent; Gravimetric analysis; Ethanol; Organic chemistry; Aqueous solution; Chromatography; Nuclear chemistry; Activity coefficient; Non-random two-liquid model","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003469354,0.0003781021,0.000251536,0.0002913251,0.0002066883,0.0002170873,0.0003181657,0.0002411353,0.0005294598],"category_scores_gemma":[0.0006118341,0.0001985828,0.000225461,0.0002594787,0.0004209775,0.0004763907,0.0001817717,0.0002929771,0.0002358447],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003277686,"about_ca_system_score_gemma":0.0002258591,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001326823,"about_ca_topic_score_gemma":0.001241813,"domain_scores_codex":[0.9997647,0.00002828018,0.00001870946,0.00005941581,0.0001085128,0.00002035954],"domain_scores_gemma":[0.9997908,0.00007672821,0.00004537719,0.0000214484,0.00005749654,0.000008175504],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007998294,0.00001871768,0.001542096,0.00009302745,0.000007967109,0.00006142801,0.00005432948,0.001875892,0.9937745,0.0001932226,0.00003272875,0.002266085],"study_design_scores_gemma":[0.000003782108,0.00007062672,0.001848017,0.000003505399,0.000005806806,0.00004205205,0.00002690859,0.00677077,0.9908172,0.00006820607,0.0003361395,0.000007013756],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9869153,0.0007021698,0.01074378,0.00004007508,0.000009960276,0.00002620922,0.000376595,0.00007961351,0.001106423],"genre_scores_gemma":[0.9931329,0.0006068288,0.005542618,0.00001233106,0.000005417,0.00003334894,0.0002841873,0.00002047433,0.0003619711],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001326823,"threshold_uncertainty_score":0.002638161,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02952411130575763,"score_gpt":0.2456037750616005,"score_spread":0.2160796637558429,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}