{"id":"W2318681269","doi":"10.1021/la305170c","title":"What Happens to the Thiolates Created by Reductively Desorbing SAMs? An in Situ Study Using Fluorescence Microscopy and Electrochemistry","year":2013,"lang":"en","type":"article","venue":"Langmuir","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemistry; Desorption; Microelectrode; Monolayer; Cyclic voltammetry; Fluorescence; Quenching (fluorescence); Electrochemistry; Adsorption; Electrode; Analytical Chemistry (journal); Inorganic chemistry; Photochemistry; Chromatography; Organic chemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005225447,0.0001169679,0.0001009672,0.0000378563,0.00008918437,0.0001754003,0.0001019141,0.00004782885,0.00001469285],"category_scores_gemma":[0.000009158303,0.00008925697,0.00001190215,0.000172255,0.00001622487,0.0001964881,0.00002713999,0.0001323324,0.000004504354],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003261813,"about_ca_system_score_gemma":0.000005000744,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002672965,"about_ca_topic_score_gemma":0.00008820725,"domain_scores_codex":[0.9994448,0.0000257056,0.0001002631,0.0001706192,0.0000622181,0.0001963361],"domain_scores_gemma":[0.9997613,0.00001061792,0.00001275946,0.0001480548,0.00002050246,0.00004675615],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000004494274,0.00001512229,0.001416008,0.000007048599,0.00001277425,0.000001980801,0.001438943,0.0001631188,0.9959054,0.000001853027,0.0003415811,0.0006916822],"study_design_scores_gemma":[0.0002182657,0.00005498136,0.02507414,0.00004104851,0.0000145907,0.00001898965,0.003741824,0.002626166,0.9677665,0.00003495446,0.0002079262,0.0002005743],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985917,0.000756727,0.0001398516,0.0000548309,0.00006784499,0.0002820713,0.000001831485,0.00005707077,0.00004804425],"genre_scores_gemma":[0.9992116,0.00002991821,0.0006212175,0.00003997538,0.00003130781,0.00001868709,0.000006711065,0.00001945687,0.00002113373],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02813886,"threshold_uncertainty_score":0.3639793,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006541988075006154,"score_gpt":0.2286816073444828,"score_spread":0.2221396192694766,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}