{"id":"W2318796264","doi":"10.1139/v06-118","title":"Synthesis and characterization of [M<sup>II</sup>(bqb)] (M = Co, Ni, Cu), [N(<i>n</i>-Bu)<sub>4</sub>][Co<sup>III</sup>(bqb)(CN)<sub>2</sub>], and [N(<i>n</i>-Bu)<sub>4</sub>][Co<sup>III</sup>(bqb)(N<sub>3</sub>)<sub>2</sub>] containing deprotonated <i>N</i>,<i>N</i>'-bis(2-quinolinecarboxamide)-1,2-benzene (bqb) X-ray crystal structures of [Ni<sup>II</sup>(bqb)] and [N(<i>n</i>-Bu)<sub>4</sub>][Co<sup>III</sup>(bqb)(N<sub>3</sub>)<sub>2</sub>]","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Monoclinic crystal system; Crystallography; Crystal structure; Octahedron; Nickel; Ligand (biochemistry); NMR spectra database; Hydrogen bond; Infrared spectroscopy; Stereochemistry; Molecule; Spectral line","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001385313,0.0002128317,0.0002076088,0.0001162095,0.0002069303,0.0002000201,0.0003365024,0.0002770905,0.001746605],"category_scores_gemma":[0.0003486829,0.0001666148,0.00007565523,0.0002091099,0.0001441402,0.0001241619,0.0001360467,0.0002311223,0.000575949],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003716613,"about_ca_system_score_gemma":0.0002928891,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002973351,"about_ca_topic_score_gemma":0.005520511,"domain_scores_codex":[0.999898,0.00001078879,0.000007414211,0.00002232606,0.0000463508,0.00001520566],"domain_scores_gemma":[0.9998616,0.00001038137,0.00003176161,0.00001674573,0.00005010951,0.00002945534],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006340902,0.00001828555,0.0001940964,0.00008109519,0.000002692359,0.00002719856,0.00003621945,0.0001323598,0.9971999,0.0001518681,0.0001998663,0.001892942],"study_design_scores_gemma":[0.000019166,0.0001368606,0.002868582,0.00000753009,0.000005874589,0.0001421602,0.00003329419,0.0008240592,0.9864426,0.00003305741,0.009479533,0.000007319206],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9692011,0.002217487,0.01934169,0.0002678608,0.00005014414,0.0002147164,0.001356724,0.0002837561,0.007066674],"genre_scores_gemma":[0.9672713,0.0009210223,0.0175835,0.0001156154,0.00001191057,0.0001742784,0.002507744,0.0001086578,0.01130603],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002973351,"threshold_uncertainty_score":0.005912066,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01169491253624238,"score_gpt":0.2125569750607944,"score_spread":0.200862062524552,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}