{"id":"W2318796264","doi":"10.1139/v06-118","title":"Synthesis and characterization of [M<sup>II</sup>(bqb)] (M = Co, Ni, Cu), [N(<i>n</i>-Bu)<sub>4</sub>][Co<sup>III</sup>(bqb)(CN)<sub>2</sub>], and [N(<i>n</i>-Bu)<sub>4</sub>][Co<sup>III</sup>(bqb)(N<sub>3</sub>)<sub>2</sub>] containing deprotonated <i>N</i>,<i>N</i>'-bis(2-quinolinecarboxamide)-1,2-benzene (bqb) X-ray crystal structures of [Ni<sup>II</sup>(bqb)] and [N(<i>n</i>-Bu)<sub>4</sub>][Co<sup>III</sup>(bqb)(N<sub>3</sub>)<sub>2</sub>]","year":2006,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Monoclinic crystal system; Crystallography; Crystal structure; Octahedron; Nickel; Ligand (biochemistry); NMR spectra database; Hydrogen bond; Infrared spectroscopy; Stereochemistry; Molecule; Spectral line","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","metaepi_broad","sts","scholarly_communication","open_science","research_integrity"],"consensus_categories":["metaepi_narrow","sts","research_integrity"],"category_scores_codex":[0.01058648,0.01328559,0.01838215,0.007819782,0.006803436,0.003502498,0.00716236,0.008527693,0.0002751713],"category_scores_gemma":[0.005508298,0.01406025,0.006135815,0.007522282,0.008795104,0.007295061,0.002825714,0.01254442,0.0002794114],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.004955663,"about_ca_system_score_gemma":0.01043379,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002116066,"about_ca_topic_score_gemma":0.002733463,"domain_scores_codex":[0.9411431,0.004792372,0.0189559,0.01132806,0.01045702,0.01332357],"domain_scores_gemma":[0.9537606,0.00469911,0.0132746,0.008588228,0.007110453,0.01256701],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.009012098,0.002535609,0.005617062,0.007238255,0.006526204,0.003687982,0.006331176,0.008446516,0.9095441,0.0001729058,0.01249679,0.02839128],"study_design_scores_gemma":[0.02291634,0.003841633,0.005354326,0.009034552,0.006986017,0.009396888,0.006301995,0.01081356,0.9072974,0.0007558026,0.005146301,0.01215516],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9581323,0.01530013,0.0006289015,0.001996225,0.001471552,0.01077535,0.008342447,0.001559241,0.001793913],"genre_scores_gemma":[0.9625791,0.01511957,0.0006002311,0.003531679,0.006802343,0.001901604,0.005674606,0.003651006,0.0001398745],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01623612,"threshold_uncertainty_score":0.9988641,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01169491253624238,"score_gpt":0.2125569750607944,"score_spread":0.200862062524552,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}