{"id":"W2318988652","doi":"10.1021/om300873k","title":"Preparation and Reactivity Study of Chromium(III), Iron(II), and Cobalt(II) Complexes of 1,3-Bis(imino)benzimidazol-2-ylidene and 1,3-Bis(imino)pyrimidin-2-ylidene","year":2012,"lang":"en","type":"article","venue":"Organometallics","topic":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Cobalt; Chromium; Methylaluminoxane; Ligand (biochemistry); Metal; Polymer chemistry; Carbene; Reactivity (psychology); Medicinal chemistry; Halide; Polymerization; Ethylene; Copper; Inorganic chemistry; Organic chemistry; Metallocene; Catalysis; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004454252,0.0006286281,0.001178136,0.0001249063,0.0003775379,0.00006311381,0.0003680098,0.0004077392,0.0007715492],"category_scores_gemma":[0.0002323352,0.0006435378,0.0001038441,0.000304312,0.0005249197,0.0005715104,0.00115109,0.0003959491,0.000001754313],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000145946,"about_ca_system_score_gemma":0.0001035377,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000314699,"about_ca_topic_score_gemma":0.00008436078,"domain_scores_codex":[0.9968084,0.00006043283,0.001094588,0.0008348295,0.0005927166,0.0006090323],"domain_scores_gemma":[0.997353,0.0002791779,0.0008018439,0.00101777,0.0001645549,0.0003836944],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001794115,0.001387407,0.02344652,0.0006062763,0.0002466362,0.000003113696,0.003789322,0.000002578605,0.9687706,0.000238589,0.0001629845,0.001166521],"study_design_scores_gemma":[0.00303579,0.000432584,0.02530389,0.00009240218,0.0006569512,0.0002137619,0.003222825,0.0000598614,0.9641265,0.00008586408,0.002010804,0.0007588108],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938598,0.002861312,0.00001972736,0.00007524909,0.000140921,0.0003530894,0.0001007666,0.00008526275,0.002503841],"genre_scores_gemma":[0.9975963,0.0008634425,0.0002428744,0.0000276808,0.0002721997,0.00002015786,0.00006803455,0.00009275666,0.0008165086],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00464419,"threshold_uncertainty_score":0.9996016,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01814317170998838,"score_gpt":0.2664337065689998,"score_spread":0.2482905348590115,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}