{"id":"W2319049048","doi":"10.1021/om100909m","title":"Differing Reactions of Functionalized Hydrocarbons with Cp*M(NO)(alkyl)(η<sup>3</sup>-allyl) Complexes of Molybdenum and Tungsten","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia, Okanagan Campus; University of British Columbia","funders":"State Key Laboratory of Resources and Environmental Information System","keywords":"Chemistry; Molybdenum; Alkyl; Medicinal chemistry; Halogen; Tungsten; Hydrocarbon; Molecule; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001604575,0.000359477,0.0007836366,0.0002215553,0.0001219322,0.00002457549,0.000347224,0.0001344848,0.02528937],"category_scores_gemma":[0.0001021978,0.0003126865,0.0002115893,0.0005045394,0.0003764135,0.0001808608,0.0001888108,0.0001897593,0.00002422364],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004536313,"about_ca_system_score_gemma":0.00006668132,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002519595,"about_ca_topic_score_gemma":0.00002569431,"domain_scores_codex":[0.9980463,0.0000313848,0.0006910558,0.000478602,0.0004249098,0.0003277002],"domain_scores_gemma":[0.9983389,0.000164871,0.0004198917,0.0007520985,0.0001468415,0.0001773762],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002713816,0.000895243,0.01303702,0.0006381415,0.001707167,0.00000975456,0.001452863,0.00002155295,0.9746959,0.003626574,0.0000255082,0.003618901],"study_design_scores_gemma":[0.005059245,0.0006540043,0.07591484,0.0006050467,0.003624822,0.0003086738,0.004588502,0.001919952,0.8508813,0.002803147,0.0510174,0.002623065],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9526374,0.0004201543,0.0003120659,0.00003290205,0.00002537829,0.0001026025,0.0000943205,0.00008396844,0.04629125],"genre_scores_gemma":[0.9913635,0.0001248595,0.001472337,0.00001451853,0.00006568446,0.00002377436,0.00006354223,0.00007791325,0.006793926],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1238146,"threshold_uncertainty_score":0.9999325,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02030878834473974,"score_gpt":0.1944167407187444,"score_spread":0.1741079523740047,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}