{"id":"W2319229815","doi":"10.1021/am302971q","title":"Localized In situ Generation of Diazonium Cations by Electrocatalytic Formation of a Diazotization Reagent","year":2013,"lang":"en","type":"article","venue":"ACS Applied Materials & Interfaces","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Reagent; In situ; Materials science; Diazonium Compounds; Combinatorial chemistry; Inorganic chemistry; Organic chemistry; Polymer chemistry; Chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001018893,0.0001368257,0.0002947943,0.00006785811,0.00003294183,0.00003502752,0.0001769125,0.0001021318,0.0003116969],"category_scores_gemma":[0.00002067579,0.0001266684,0.00001785161,0.0002034888,0.00004622966,0.0001443372,0.00003943955,0.00005607081,0.00003362831],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006186171,"about_ca_system_score_gemma":0.00001968038,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002015028,"about_ca_topic_score_gemma":0.00006482873,"domain_scores_codex":[0.9987497,0.00001389626,0.0007136339,0.0002043126,0.0001489824,0.0001694242],"domain_scores_gemma":[0.9992099,0.00003606683,0.0003897761,0.0002464771,0.00009061491,0.00002716534],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001359909,0.0001294688,0.00001553918,0.0001181716,0.00002127302,1.349751e-8,0.0001777093,0.0000478537,0.9976302,0.0008603059,0.000588591,0.0003972492],"study_design_scores_gemma":[0.0002427879,0.00001286792,0.00001646612,0.00002237231,0.00004033862,4.005462e-7,0.00009875723,0.0001046353,0.9984978,0.0008183545,0.00003413514,0.0001110276],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970381,0.0001021374,0.001454766,0.0001213277,0.00001006293,0.0002227503,0.0000313769,0.00002375053,0.0009957853],"genre_scores_gemma":[0.9981906,0.0001345637,0.0001640871,0.00002226279,0.000030771,0.0003812592,0.0009745528,0.00001449011,0.00008738288],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001290679,"threshold_uncertainty_score":0.5165388,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01005009802192755,"score_gpt":0.2225965946772974,"score_spread":0.2125464966553699,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}