{"id":"W2319254312","doi":"10.1021/ic402133c","title":"Square-Planar Cu(II) Diketiminate Complexes in Lactide Polymerization","year":2013,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"biodegradable polymer synthesis and properties","field":"Materials Science","cited_by":72,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Homoleptic; Chemistry; Polymerization; Steric effects; Lactide; Monomer; Benzyl alcohol; Polymer chemistry; Ligand (biochemistry); Catalysis; Medicinal chemistry; Polymer; Stereochemistry; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000130044,0.0004708949,0.0001891869,0.0001137034,0.0001337773,0.0003173886,0.000235992,0.0002274303,0.000773766],"category_scores_gemma":[0.0001310088,0.0002079937,0.00008214595,0.00014127,0.0001712803,0.0001847497,0.0002522266,0.0003139868,0.0003188994],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004520924,"about_ca_system_score_gemma":0.0001284591,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006746125,"about_ca_topic_score_gemma":0.0009868583,"domain_scores_codex":[0.9998661,0.00002547467,0.000007756172,0.00003303736,0.00002569759,0.00004180741],"domain_scores_gemma":[0.9999352,0.000007105645,0.00001908737,0.000005655171,0.000009083397,0.00002398066],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007389364,0.00002092561,0.00007447277,0.00005740136,0.000005064911,0.00005524448,0.00005194022,0.0002990501,0.9967955,0.0003928448,0.00008455586,0.002089169],"study_design_scores_gemma":[0.00002753215,0.0002282508,0.0005940325,0.000006364259,0.00001099082,0.00010897,0.0000177972,0.001866595,0.9934228,0.00007094229,0.003635023,0.0000107024],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9876394,0.001580475,0.004331857,0.0000788869,0.00002679186,0.00006231921,0.00004224739,0.0001733179,0.006064679],"genre_scores_gemma":[0.9932435,0.0005091945,0.003127936,0.00002962389,0.000005735317,0.0000307449,0.00005343429,0.00001696603,0.00298288],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000773766,"threshold_uncertainty_score":0.003280103,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01194231529304023,"score_gpt":0.2035782555795653,"score_spread":0.1916359402865251,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}