{"id":"W2319268437","doi":"10.1021/cs300214v","title":"Design and Synthesis of Chiral Heteroleptic Rhodium(II) Carboxylate Catalysts: Experimental Investigation of Halogen Bond Rigidification Effects in Asymmetric Cyclopropanation","year":2012,"lang":"en","type":"article","venue":"ACS Catalysis","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":72,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Centre in Green Chemistry and Catalysis","funders":"","keywords":"Rhodium; Cyclopropanation; Catalysis; Chemistry; Halogen; Halogen bond; Carboxylate; Combinatorial chemistry; Organic chemistry; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004033009,0.0002292438,0.0004258305,0.0005556726,0.00007025029,0.00001301134,0.0001587122,0.0001755339,0.000006959865],"category_scores_gemma":[0.0002446547,0.0002379363,0.00008270642,0.0007458068,0.00009428775,0.0004037808,0.00008078756,0.0001202497,0.000006464886],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00026099,"about_ca_system_score_gemma":0.00003505222,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004035514,"about_ca_topic_score_gemma":0.000008234291,"domain_scores_codex":[0.9983853,0.0000873622,0.0005661743,0.0003298191,0.0003663797,0.0002649887],"domain_scores_gemma":[0.9986256,0.0002611264,0.0004925042,0.0004291685,0.00008180641,0.0001098477],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003815715,0.0001731353,0.008996787,0.0003176961,0.00007773814,8.96467e-7,0.002301674,0.0000422542,0.9833558,0.0001179151,0.000003314771,0.004574626],"study_design_scores_gemma":[0.0004715531,0.00004388114,0.004956952,0.00006086206,0.0002510292,0.000009785525,0.0008441597,0.0003172831,0.9927591,0.00008243991,0.000003580405,0.0001993458],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974023,0.001188234,0.0005673799,0.00001353824,0.00004803107,0.0002500126,0.000006644467,0.00004914342,0.0004747658],"genre_scores_gemma":[0.9967744,0.00003856639,0.002810449,0.000004829018,0.0000383205,0.0001580792,0.0001162957,0.00004042611,0.0000185947],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.009403323,"threshold_uncertainty_score":0.9702762,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01276348793609666,"score_gpt":0.2286251245594343,"score_spread":0.2158616366233377,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}