{"id":"W2319335400","doi":"10.1021/jp4022272","title":"Role of (NO)<sub>2</sub> Dimer in Reactions of Fe<sup>+</sup> with NO and NO<sub>2</sub> Studied by ICP-SIFT Mass Spectrometry","year":2013,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry A","topic":"Catalytic Processes in Materials Science","field":"Materials Science","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Chemistry; Dimer; Branching (polymer chemistry); Branching fraction; Order (exchange); Impurity; Computational chemistry; Physics; Nuclear physics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0008415185,0.00027213,0.0006554417,0.00005398362,0.00009080857,0.00006449905,0.000723627,0.00007934332,0.00008152921],"category_scores_gemma":[0.0004984757,0.0001818231,0.00009067571,0.0004220135,0.0007711468,0.0005189193,0.0002115935,0.0003671353,0.00007926628],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009399999,"about_ca_system_score_gemma":0.0001564662,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003557759,"about_ca_topic_score_gemma":8.066463e-7,"domain_scores_codex":[0.9977546,0.00008125669,0.0007052845,0.0002903724,0.0007631956,0.0004053215],"domain_scores_gemma":[0.9975436,0.0003964738,0.0008721511,0.0004407893,0.0005809047,0.000166051],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002368186,0.0003232814,0.00002796401,0.0002455636,0.00003315968,0.00000235619,0.0003482133,0.0003830696,0.9979742,0.000008530548,0.0003706734,0.00004621445],"study_design_scores_gemma":[0.0006001175,0.0002609263,0.0001974121,0.0002298734,0.00007720245,0.00006419985,0.0003808262,0.001139895,0.9958501,0.000980941,0.00002328325,0.000195225],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984375,0.0001215094,0.0001233261,0.00009557095,0.00004804877,0.0001611836,0.0000359291,0.00001318461,0.0009637519],"genre_scores_gemma":[0.9992434,0.00008196617,0.0002825737,0.00002468647,0.0003017999,0.000009926584,0.00000206187,0.0000229882,0.00003064106],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002124058,"threshold_uncertainty_score":0.741453,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004381330922425213,"score_gpt":0.2109442948496138,"score_spread":0.2065629639271886,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}