{"id":"W2319367645","doi":"10.1021/jo201862s","title":"Peroxyesters As Precursors to Peroxyl Radical Clocks","year":2011,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Queen's University","funders":"Ontario Ministry of Research and Innovation; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Reaction rate constant; Radical; Photochemistry; Solvent; Combinatorial chemistry; Organic chemistry; Kinetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006096485,0.0004207015,0.0002503519,0.0002664517,0.0001869991,0.000306627,0.0005296996,0.000269024,0.002005989],"category_scores_gemma":[0.0008052794,0.000231085,0.0002140467,0.0002090833,0.0002097083,0.0007026246,0.0003526549,0.001178712,0.0006516625],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002574084,"about_ca_system_score_gemma":0.0003397456,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002483866,"about_ca_topic_score_gemma":0.0005930153,"domain_scores_codex":[0.9996573,0.00008031306,0.00002314561,0.00007210443,0.0001016228,0.00006551536],"domain_scores_gemma":[0.9994785,0.0001518198,0.0001270869,0.00006632193,0.0001167807,0.00005949966],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002120967,0.00005099169,0.0002354441,0.0002235003,0.00001282416,0.0000928978,0.0001393563,0.0002622752,0.9910145,0.002394727,0.0002052421,0.00515603],"study_design_scores_gemma":[0.00001071464,0.0002448657,0.0002024467,0.000007474028,0.000006507099,0.00004080387,0.00001698645,0.0003537314,0.9955095,0.0001253261,0.003476439,0.000005213599],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9419725,0.00478921,0.04573015,0.0002101374,0.0002486421,0.0002338469,0.0004874863,0.0003553393,0.005972736],"genre_scores_gemma":[0.9663503,0.002845778,0.0219294,0.00006764295,0.00003916725,0.0001351348,0.0006517019,0.0001281138,0.007852712],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002005989,"threshold_uncertainty_score":0.006710708,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01458104048091518,"score_gpt":0.2190526801215474,"score_spread":0.2044716396406323,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}