{"id":"W2319367645","doi":"10.1021/jo201862s","title":"Peroxyesters As Precursors to Peroxyl Radical Clocks","year":2011,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa; Queen's University","funders":"Ontario Ministry of Research and Innovation; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Reaction rate constant; Radical; Photochemistry; Solvent; Combinatorial chemistry; Organic chemistry; Kinetics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004041429,0.0002116841,0.0002988638,0.00001988472,0.0001088967,0.00002648417,0.0009590749,0.0001618681,0.02054331],"category_scores_gemma":[0.000296255,0.0001431328,0.0001704889,0.0001382054,0.0001782686,0.00008270941,0.0001216547,0.0006300309,0.0001105059],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00009455451,"about_ca_system_score_gemma":0.0001890602,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001185013,"about_ca_topic_score_gemma":0.000001488004,"domain_scores_codex":[0.9985116,0.00002341732,0.0005196688,0.0001521504,0.0004559111,0.0003372876],"domain_scores_gemma":[0.9987029,0.00008326169,0.0003014029,0.000418402,0.00009884347,0.0003951536],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001692654,0.0001477891,0.0005943522,0.0000674097,0.0000981538,0.00007391215,0.001626521,0.000001255104,0.9930052,0.000007542485,0.003057957,0.0011507],"study_design_scores_gemma":[0.000629662,0.00006407693,0.0003392292,0.0001877173,0.0001165011,0.002177244,0.00117195,0.000005641558,0.9885224,0.0002123751,0.00636238,0.0002108189],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9761922,0.0004081075,0.0001011461,0.0007190771,0.0001149755,0.00002779877,0.000003964554,0.00002736281,0.02240532],"genre_scores_gemma":[0.9957066,0.0001573567,0.0003200949,0.0002508634,0.0005554782,8.208115e-7,8.03812e-7,0.00004134684,0.002966705],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02043281,"threshold_uncertainty_score":0.980352,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01458104048091518,"score_gpt":0.2190526801215474,"score_spread":0.2044716396406323,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}