{"id":"W2319417914","doi":"10.1021/om500212x","title":"18-Electron Ruthenium Phosphine Sulfonate Catalysts for Olefin Metathesis","year":2014,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Ruthenium; Chemistry; Phosphine; Metathesis; Ring-opening metathesis polymerisation; Acyclic diene metathesis; Salt metathesis reaction; Catalysis; Ligand (biochemistry); Olefin metathesis; Ring-closing metathesis; Sulfonate; ROMP; Chelation; Organic chemistry; Medicinal chemistry; Combinatorial chemistry; Polymer chemistry; Polymerization; Sodium; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002551998,0.0004649542,0.0003179019,0.0003128764,0.0002206888,0.0005347999,0.0004807832,0.0004191108,0.001687802],"category_scores_gemma":[0.0003487181,0.0001958315,0.0002061882,0.0002358201,0.0002683295,0.0005651895,0.0005353826,0.0005819796,0.0006567768],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006285443,"about_ca_system_score_gemma":0.0002572597,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002482526,"about_ca_topic_score_gemma":0.0005044929,"domain_scores_codex":[0.9997942,0.00003192211,0.00002120444,0.00002500856,0.00007758696,0.00005014935],"domain_scores_gemma":[0.9999326,0.00001859683,0.00001464528,0.00001291262,0.00000902102,0.00001211659],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003524761,0.0001064789,0.0005966239,0.0006381982,0.00005380806,0.0007284446,0.0003056871,0.002685004,0.9345346,0.02179041,0.001464196,0.03674408],"study_design_scores_gemma":[0.00004145081,0.0002512361,0.0002662053,0.00001662454,0.00002382723,0.0003118321,0.0000235519,0.001827498,0.9833502,0.0005996783,0.01327463,0.0000133092],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9396772,0.007136901,0.02067696,0.0005544985,0.0001638087,0.0001139654,0.0002890395,0.0007074462,0.03068019],"genre_scores_gemma":[0.9915788,0.00193044,0.003857959,0.0000360316,0.00001481516,0.00002096774,0.00009770905,0.00004857519,0.002414855],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001687802,"threshold_uncertainty_score":0.005646229,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01883036197164957,"score_gpt":0.2677164382374636,"score_spread":0.248886076265814,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}